Home
Class 11
CHEMISTRY
Do NH(3) and BF(3) have same shape ?...

Do `NH_(3)` and `BF_(3)` have same shape ?

Text Solution

AI Generated Solution

The correct Answer is:
To determine if \( NH_3 \) (ammonia) and \( BF_3 \) (boron trifluoride) have the same shape, we can analyze their molecular structures based on their valence electrons and bonding. ### Step-by-Step Solution: 1. **Identify the Valence Electrons:** - For \( NH_3 \): Nitrogen (N) has 5 valence electrons (configuration: \( 1s^2 2s^2 2p^3 \)). Each hydrogen (H) has 1 valence electron. Thus, the total number of valence electrons in \( NH_3 \) is \( 5 + 3(1) = 8 \). - For \( BF_3 \): Boron (B) has 3 valence electrons (configuration: \( 1s^2 2s^2 2p^1 \)). Each fluorine (F) has 7 valence electrons. Thus, the total number of valence electrons in \( BF_3 \) is \( 3 + 3(7) = 24 \). 2. **Determine the Bonding Pairs and Lone Pairs:** - In \( NH_3 \): Nitrogen forms three bonds with hydrogen atoms, using 3 of its valence electrons. This leaves 1 lone pair of electrons on the nitrogen atom. - In \( BF_3 \): Boron forms three bonds with fluorine atoms, using all of its valence electrons. There are no lone pairs on the boron atom. 3. **Determine the Molecular Geometry:** - For \( NH_3 \): The presence of one lone pair and three bond pairs leads to a trigonal pyramidal shape. The lone pair pushes the hydrogen atoms down, creating a pyramid shape. - For \( BF_3 \): With no lone pairs and three bond pairs, the shape is trigonal planar. The three fluorine atoms are arranged in a flat plane around the boron atom. 4. **Conclusion:** - Since \( NH_3 \) has a trigonal pyramidal shape and \( BF_3 \) has a trigonal planar shape, they do not have the same shape. ### Final Answer: No, \( NH_3 \) and \( BF_3 \) do not have the same shape. \( NH_3 \) is trigonal pyramidal, while \( BF_3 \) is trigonal planar. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

Both NH_(3) and NF_(3) have identical shapes and same state of hybridisation. Both N-H and N-F bonds have almost the same electronegativity difference. But still, the two molecules have different dipole moment values. How will you account for it ?

BF_(3) is.

The tendency of bF_(3), BCl_(3) and BBr_(3) behave as Lewis acid decreases in the sequnece (a) BCl_(3) gt BF_(3) gt BBr_(3) (b) BBr_(3) gt BCl_(3) gt BF_(3) (c) BBr_(3) gt BF_(3) gt BCl_(3) (d) BF_(3) gt BCl_(3) gt BBr_(3)

Which of the following statement is not correct ? (a) [Ni(H_(2)O)_(6)]^(2+) and [Ni(NH_(3))_(6)]^(2+) have same value of CFSE ( b) [Ni(H_(2)O)_(6)]^(2+) and [Ni(NH_(3))_(6)]^(2+) have same value of magnetic moment

NH_(3) and BF_(3) from adduct readily because they from

In the following questions, a statement of assertion (A) is followed by a statement of reason (R ) A: bond angle of BF_(3) and NF_(3) are different. R : Both the molecules are having different shape

(a) BF_(3) and BrF_(3) molecule has different shapes. Expain. (b). C Cl_(4) cannot be hydrolysed but SiCl_(4) can be, why?

He_(2)^(3) and He_(1)^(3) nuclei have the same mass number. Do they have the same binding energy ?

BF_(3)+HFto

Describe the shapes of BF_(3) and BH_(4)^(-) . Assign the hybridisation of boron atom in these species.