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Define electronegatively....

Define electronegatively.

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**Step-by-Step Solution:** 1. **Definition of Electronegativity:** Electronegativity is defined as the tendency of an atom to attract a shared pair of electrons when it forms a chemical bond. 2. **Understanding Shared Pair of Electrons:** In a covalent bond, two atoms share a pair of electrons. These shared electrons are what electronegativity refers to. 3. **Example of Electronegativity:** Consider the molecule hydrogen fluoride (HF). In this molecule, there is a covalent bond between hydrogen and fluorine. 4. **Comparison of Electronegativity:** Fluorine is more electronegative than hydrogen, meaning it has a greater tendency to attract the shared pair of electrons in the bond. 5. **Result of Electronegativity:** As a result of this difference in electronegativity, the shared electrons are pulled closer to the fluorine atom, giving it a partial negative charge, while the hydrogen atom acquires a partial positive charge. 6. **Electronegativity Value:** The electronegativity of fluorine is approximately 3.98 on the Pauling scale, which indicates its strong ability to attract electrons.
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Mulliken defined the electronegativity of an atom as the arithmetic mean of its ionisation energy and electron affinity. X_(A)=(1)/(2)(I.P.+E.A.) One more relationship given by him, if the values are given in eV is X_(A)=("Ionisation potential"+ "Electron affinity")/(5.6) When there is pure covalent bond between A-B ((IP)_(A)+(EA)_(A))/(5.6)=((IP)_(B)+(EA)_(B))/(5.6) implies X_(A)=X_(B) When there is formation of overset(delta-)(A)-overset(delta+)(B) bond then condition will be