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The structure of lCl(2)^(-) is:...

The structure of `lCl_(2)^(-)` is:

A

trigonal

B

trigonal bipyramidal

C

octahedral

D

square planar.

Text Solution

AI Generated Solution

The correct Answer is:
To determine the structure of the ion \( \text{ICl}_2^- \), we can follow these steps: ### Step 1: Count the Valence Electrons First, we need to count the total number of valence electrons in the ion. - Iodine (I) is in group 17 and has 7 valence electrons. - Each chlorine (Cl) atom also has 7 valence electrons, and there are 2 chlorine atoms, contributing \( 2 \times 7 = 14 \) electrons. - The negative charge on the ion indicates that we have one extra electron. So, the total number of valence electrons is: \[ 7 \, (\text{from I}) + 14 \, (\text{from 2 Cl}) + 1 \, (\text{extra from negative charge}) = 22 \, \text{valence electrons} \] ### Step 2: Draw the Lewis Structure Next, we will draw the Lewis structure for \( \text{ICl}_2^- \). - Place iodine in the center because it is less electronegative than chlorine. - Connect the two chlorine atoms to iodine with single bonds. This uses 4 electrons (2 for each bond). - Now, we have \( 22 - 4 = 18 \) electrons left. - Distribute the remaining electrons to satisfy the octet rule. Each chlorine will get 6 electrons (3 lone pairs), using up 12 electrons, leaving us with \( 18 - 12 = 6 \) electrons. - Place the remaining 6 electrons as 3 lone pairs on the iodine atom. ### Step 3: Determine the Molecular Geometry Now we need to determine the molecular geometry of \( \text{ICl}_2^- \). - Iodine has 2 bonded pairs (from the I-Cl bonds) and 3 lone pairs. - According to VSEPR theory, the arrangement of electron pairs around the central atom (iodine) will be trigonal bipyramidal. - However, since we are only considering the bonded pairs for the molecular shape, the shape of \( \text{ICl}_2^- \) will be linear, as the lone pairs will occupy the equatorial positions to minimize repulsion. ### Step 4: Final Structure The final structure of \( \text{ICl}_2^- \) can be represented as follows: - Iodine in the center with two chlorine atoms at opposite ends, and three lone pairs on iodine. ### Summary - The Lewis structure shows iodine with two single bonds to chlorine and three lone pairs. - The molecular geometry is linear due to the arrangement of the bonded pairs. ### Final Answer The structure of \( \text{ICl}_2^- \) is linear with a trigonal bipyramidal electron geometry. ---

To determine the structure of the ion \( \text{ICl}_2^- \), we can follow these steps: ### Step 1: Count the Valence Electrons First, we need to count the total number of valence electrons in the ion. - Iodine (I) is in group 17 and has 7 valence electrons. - Each chlorine (Cl) atom also has 7 valence electrons, and there are 2 chlorine atoms, contributing \( 2 \times 7 = 14 \) electrons. - The negative charge on the ion indicates that we have one extra electron. ...
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