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Hybridisation and shape of BrF(5) is :...

Hybridisation and shape of `BrF_(5)` is :

A

`sp^(3)d` (Trigonal bipyramidal)

B

`sp^(3)d^(2)` (Octahedral)

C

`dsp^(2)` (Square planar)

D

`sp^(3)d^(2)` (Square pyramidal)

Text Solution

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The correct Answer is:
To determine the hybridization and shape of BrF₅ (Bromine Pentafluoride), we can follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is a halogen and has 7 valence electrons. Each Fluorine (F) atom has 7 valence electrons as well. In BrF₅, there are 5 Fluorine atoms. - Total valence electrons from Br = 7 - Total valence electrons from 5 F = 5 × 7 = 35 - Total valence electrons = 7 (Br) + 35 (5 F) = 42 ### Step 2: Draw the Lewis Structure In the Lewis structure of BrF₅, Bromine will form 5 single bonds with 5 Fluorine atoms. After forming these bonds, Bromine will have 1 lone pair of electrons remaining. - Bond pairs: 5 (Br-F bonds) - Lone pairs: 1 (on Br) ### Step 3: Determine the Hybridization To find the hybridization, we can use the formula: \[ \text{Hybridization} = \text{Number of bond pairs} + \text{Number of lone pairs} \] In BrF₅: - Number of bond pairs = 5 - Number of lone pairs = 1 So, the total is: \[ 5 + 1 = 6 \] The hybridization corresponding to 6 regions of electron density is sp³d². ### Step 4: Determine the Molecular Shape With 5 bond pairs and 1 lone pair, the molecular geometry is determined by the arrangement of the bond pairs. The shape of BrF₅ is square pyramidal. ### Conclusion - **Hybridization of BrF₅**: sp³d² - **Shape of BrF₅**: Square pyramidal

To determine the hybridization and shape of BrF₅ (Bromine Pentafluoride), we can follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is a halogen and has 7 valence electrons. Each Fluorine (F) atom has 7 valence electrons as well. In BrF₅, there are 5 Fluorine atoms. - Total valence electrons from Br = 7 - Total valence electrons from 5 F = 5 × 7 = 35 - Total valence electrons = 7 (Br) + 35 (5 F) = 42 ...
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