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The cyanide ion CN and N(2) are isoelect...

The cyanide ion `CN and N_(2)` are isoelectronic, but in contrast to `CN^(-), N_(2)` is chemically inert, because of

A

low bond energy

B

absence of bond polairty

C

unsymmetical electron distribution

D

Presence of more number of electron is bonding orbitals.

Text Solution

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The correct Answer is:
To solve the question regarding why the cyanide ion (CN⁻) is chemically reactive while nitrogen gas (N₂) is chemically inert, even though they are isoelectronic, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Isoelectronic Species**: - Both CN⁻ and N₂ have the same number of electrons. CN⁻ has 14 electrons (6 from carbon and 7 from nitrogen, plus 1 extra due to the negative charge), and N₂ also has 14 electrons (7 from each nitrogen atom). 2. **Identifying the Nature of the Molecules**: - CN⁻ is a heteroatomic ion consisting of carbon and nitrogen, while N₂ is a homoatomic molecule made up of two nitrogen atoms. 3. **Bonding Characteristics**: - In CN⁻, the presence of a negative charge leads to a polar bond due to the difference in electronegativity between carbon and nitrogen. This polar nature contributes to its reactivity. - In contrast, N₂ has a triple bond between two nitrogen atoms, which is non-polar because both atoms are the same. This lack of polarity contributes to its stability and inertness. 4. **Bond Energy Considerations**: - The bond in N₂ is very strong (triple bond), which contributes to its inertness. High bond energy means that it requires a significant amount of energy to break the bond, making it less reactive. - CN⁻, on the other hand, has a polar bond that can participate in chemical reactions more readily. 5. **Conclusion**: - The key reason for the chemical inertness of N₂ compared to the reactivity of CN⁻ is the **absence of bond polarity** in N₂, which makes it stable and less likely to react with other substances. ### Final Answer: The correct option is **B: Absence of bond polarity**.

To solve the question regarding why the cyanide ion (CN⁻) is chemically reactive while nitrogen gas (N₂) is chemically inert, even though they are isoelectronic, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Isoelectronic Species**: - Both CN⁻ and N₂ have the same number of electrons. CN⁻ has 14 electrons (6 from carbon and 7 from nitrogen, plus 1 extra due to the negative charge), and N₂ also has 14 electrons (7 from each nitrogen atom). 2. **Identifying the Nature of the Molecules**: ...
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