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Statement 1: The B.O. of F(2) molecule i...

Statement 1: The B.O. of `F_(2)` molecule is 1.
Statement 2: In `F_(2)` molecule, the number of electrons in the antibonding M.O. is two less than in bonding M.O.

A

Statemetn-1 is true, Statrment-2 is also true, Statement -2 is the correct explanation of statement-1

B

Statement -1 is true , Statement 2 is also true, Statement-2 is not the correct explanation of Statement-1

C

Statement-1 is true, Statement-2 is false.

D

Statement-1 is false, Statement-2 is true.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding the `F2` molecule and determine their validity. ### Step-by-Step Solution: 1. **Understanding the Molecular Orbital Configuration of `F2`:** - The total number of electrons in a `F2` molecule is 18 (since each fluorine atom contributes 9 electrons). - The molecular orbital (MO) configuration for `F2` can be written as: - σ1s², σ*1s², σ2s², σ*2s², σ2p_z², π2p_x², π2p_y², π*2p_x², π*2p_y². - Here, the asterisk (*) indicates antibonding orbitals. 2. **Counting Electrons in Bonding and Antibonding Orbitals:** - **Bonding Electrons:** - From the configuration, the bonding MOs are σ1s, σ2s, σ2p_z, π2p_x, and π2p_y. - Total bonding electrons = 2 (σ1s) + 2 (σ2s) + 2 (σ2p_z) + 2 (π2p_x) + 2 (π2p_y) = 10 electrons. - **Antibonding Electrons:** - The antibonding MOs are σ*1s, σ*2s, π*2p_x, and π*2p_y. - Total antibonding electrons = 2 (σ*1s) + 2 (σ*2s) + 2 (π*2p_x) + 2 (π*2p_y) = 8 electrons. 3. **Calculating the Bond Order:** - The bond order (B.O.) is calculated using the formula: \[ \text{Bond Order} = \frac{(\text{Number of Bonding Electrons} - \text{Number of Antibonding Electrons})}{2} \] - Substituting the values: \[ \text{Bond Order} = \frac{(10 - 8)}{2} = \frac{2}{2} = 1 \] - Therefore, the bond order of `F2` is indeed 1. 4. **Analyzing the Second Statement:** - The second statement claims that in `F2`, the number of electrons in the antibonding M.O. is two less than in the bonding M.O. - We found that the number of bonding electrons is 10 and the number of antibonding electrons is 8. - The difference is indeed: \[ 10 - 8 = 2 \] - Thus, the second statement is also true. 5. **Conclusion:** - Both statements are true, and the second statement correctly explains the first statement. ### Final Answer: - **Statement 1:** True (The bond order of `F2` is 1.) - **Statement 2:** True (In `F2`, the number of electrons in the antibonding M.O. is two less than in the bonding M.O.)

To solve the question, we need to analyze both statements regarding the `F2` molecule and determine their validity. ### Step-by-Step Solution: 1. **Understanding the Molecular Orbital Configuration of `F2`:** - The total number of electrons in a `F2` molecule is 18 (since each fluorine atom contributes 9 electrons). - The molecular orbital (MO) configuration for `F2` can be written as: - σ1s², σ*1s², σ2s², σ*2s², σ2p_z², π2p_x², π2p_y², π*2p_x², π*2p_y². ...
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