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Value of gas constant R is ....

Value of gas constant `R` is .

A

`0.082 J "litre" atm`

B

`0.987 cal "mol"^(-1) K^(-1)`

C

`8.314 J "mol"^(-1) K^(-1)`

D

`83 erg mol^(-1) K^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of the gas constant \( R \), we can use the ideal gas equation: \[ PV = nRT \] From this equation, we can rearrange it to express \( R \): \[ R = \frac{PV}{nT} \] ### Step 1: Identify the values needed for \( P \), \( V \), \( n \), and \( T \) - **Pressure (\( P \))**: The standard atmospheric pressure is \( 1 \, \text{atm} \), which can be converted to Pascals: \[ 1 \, \text{atm} = 101325 \, \text{Pa} \] - **Volume (\( V \))**: The molar volume of an ideal gas at standard temperature and pressure (STP) is \( 22.4 \, \text{L} \). We convert this to cubic meters: \[ 22.4 \, \text{L} = 22.4 \times 10^{-3} \, \text{m}^3 \] - **Number of moles (\( n \))**: At standard conditions, we consider \( n = 1 \, \text{mol} \). - **Temperature (\( T \))**: The standard temperature is \( 273 \, \text{K} \). ### Step 2: Substitute the values into the equation for \( R \) Now we substitute the values into the equation: \[ R = \frac{(101325 \, \text{Pa}) \times (22.4 \times 10^{-3} \, \text{m}^3)}{(1 \, \text{mol}) \times (273 \, \text{K})} \] ### Step 3: Calculate \( R \) Calculating the numerator: \[ 101325 \, \text{Pa} \times 22.4 \times 10^{-3} \, \text{m}^3 = 2270.4 \, \text{Pa} \cdot \text{m}^3 \] Now, divide by the denominator: \[ R = \frac{2270.4 \, \text{Pa} \cdot \text{m}^3}{273 \, \text{mol} \cdot \text{K}} \approx 8.314 \, \text{J} \cdot \text{mol}^{-1} \cdot \text{K}^{-1} \] ### Conclusion Thus, the value of the gas constant \( R \) is: \[ R \approx 8.314 \, \text{J} \cdot \text{mol}^{-1} \cdot \text{K}^{-1} \]

To find the value of the gas constant \( R \), we can use the ideal gas equation: \[ PV = nRT \] From this equation, we can rearrange it to express \( R \): ...
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