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Give the structures and IUPAC names of all the isomeric monochlorobutaners.

Text Solution

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The molecular formula for the isomers is `C_(4)H_(9)Cl`. The structural formulae of the different isomers are :
`{:((i)" "overset(4)(C)H_(3)-overset(3)(C)H_(2)-overset(2)(C)H_(2)-overset(1)(C)H_(2)-Cl" "(ii)" "overset(4)(C)H_(3)-overset(3)(C)H_(2)-overset(2)(C)H-overset(1)(C)H_(3)),(" 1-Chlorobutane"" |"),(" "Cl),(" 2-Chlorobutane"):}`
`{:(" ".^(1)CH_(3)),(" |"),((iii)" "overset(3)(C)H_(3)-overset(2)(C)H-overset(1)(C)H_(2)-Cl" "(iv)" "CH_(3)overset(2)(-C)-Cl),(" |"" |"),(" "CH_(3)" ".^(3)CH_(3)),(" 1-Chloro-2-methylpropane"" 2-Chloro-2-methylpropane"):}`
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