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In Duma's method, the gas collected in n...

In Duma's method, the gas collected in nitrometer is :

A

`N_(2)`

B

`NO`

C

`NH_(3)`

D

`H_(2)`

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The correct Answer is:
### Step-by-Step Solution: 1. **Understanding Duma's Method**: Duma's method is a technique used for the estimation of nitrogen in organic compounds. It involves the combustion of the organic compound in the presence of cupric oxide (CuO). 2. **Reaction Setup**: In this method, the organic compound containing nitrogen is mixed with cupric oxide and heated in a furnace. The reaction can be represented as: \[ \text{Organic Compound} + \text{CuO} \rightarrow \text{CO}_2 + \text{N}_2 + \text{H}_2\text{O} \] This reaction produces carbon dioxide (CO₂), nitrogen (N₂), and water (H₂O). 3. **Collection of Gases**: The gases produced during the reaction, specifically nitrogen, are collected in a device known as a nitrometer. The nitrometer is designed to measure the volume of gases produced. 4. **Separation of Gases**: After the reaction, the mixture contains nitrogen, carbon dioxide, and water vapor. To obtain pure nitrogen gas, it is necessary to remove CO₂ and H₂O. This is done using: - **KOH (Potassium Hydroxide)**: This absorbs carbon dioxide. - **HgCl₂ (Mercury(II) Chloride)**: This absorbs water vapor. 5. **Final Collection**: After the absorption of CO₂ and H₂O, the remaining gas in the nitrometer is pure nitrogen (N₂). ### Conclusion: Thus, in Duma's method, the gas collected in the nitrometer is nitrogen (N₂). ---

### Step-by-Step Solution: 1. **Understanding Duma's Method**: Duma's method is a technique used for the estimation of nitrogen in organic compounds. It involves the combustion of the organic compound in the presence of cupric oxide (CuO). 2. **Reaction Setup**: In this method, the organic compound containing nitrogen is mixed with cupric oxide and heated in a furnace. The reaction can be represented as: \[ \text{Organic Compound} + \text{CuO} \rightarrow \text{CO}_2 + \text{N}_2 + \text{H}_2\text{O} \] ...
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