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A compound made up of elements A and B c...

A compound made up of elements `A` and `B` crystallizes in the cubic structures. Atoms `A` are present on the corners as well as face centres whereas atoms `B` are present on the edge centres centres as well as body centre. What is the formula of the compound? Draw the structure of its unit cell.

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To determine the formula of the compound made up of elements A and B that crystallizes in a cubic structure, we need to analyze the arrangement of the atoms in the unit cell. ### Step-by-Step Solution: 1. **Identify the Positions of Atoms**: - Atoms A are located at the corners and face centers of the cubic unit cell. - Atoms B are located at the edge centers and the body center of the cubic unit cell. 2. **Calculate Contribution of Atoms A**: - **Corners**: There are 8 corners in a cube. Each corner atom contributes \( \frac{1}{8} \) of its volume to the unit cell. \[ \text{Contribution from corners} = 8 \times \frac{1}{8} = 1 \text{ atom of A} \] - **Face Centers**: There are 6 face centers in a cube. Each face-centered atom contributes \( \frac{1}{2} \) of its volume to the unit cell. \[ \text{Contribution from face centers} = 6 \times \frac{1}{2} = 3 \text{ atoms of A} \] - **Total Contribution of A**: \[ \text{Total A} = 1 + 3 = 4 \text{ atoms of A} \] 3. **Calculate Contribution of Atoms B**: - **Edge Centers**: There are 12 edges in a cube. Each edge-centered atom contributes \( \frac{1}{4} \) of its volume to the unit cell. \[ \text{Contribution from edge centers} = 12 \times \frac{1}{4} = 3 \text{ atoms of B} \] - **Body Center**: There is 1 body center in a cube. The body-centered atom contributes fully to the unit cell. \[ \text{Contribution from body center} = 1 \text{ atom of B} \] - **Total Contribution of B**: \[ \text{Total B} = 3 + 1 = 4 \text{ atoms of B} \] 4. **Determine the Empirical Formula**: - From the contributions calculated, we have: - 4 atoms of A - 4 atoms of B - Therefore, the empirical formula of the compound is: \[ \text{Formula} = A_4B_4 \] - Simplifying this gives: \[ \text{Simplest Formula} = AB \] 5. **Draw the Structure of the Unit Cell**: - The unit cell can be visualized as a cube where: - Atoms A are at the 8 corners and at the center of each face. - Atoms B are at the center of each edge and at the center of the cube. ### Summary of the Solution: The formula of the compound is \( AB \).

To determine the formula of the compound made up of elements A and B that crystallizes in a cubic structure, we need to analyze the arrangement of the atoms in the unit cell. ### Step-by-Step Solution: 1. **Identify the Positions of Atoms**: - Atoms A are located at the corners and face centers of the cubic unit cell. - Atoms B are located at the edge centers and the body center of the cubic unit cell. ...
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