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In a crystalline solid, anions B are arr...

In a crystalline solid, anions `B` are arranged in ccp structure. Cations `A` are equally distributed between octahedral and tetrahedral voids if all the octahedral voids are occupied the formula of the ionic solids will be

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To determine the formula of the ionic solid based on the arrangement of anions and cations, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Arrangement of Anions**: - The anions `B` are arranged in a cubic close-packed (CCP) structure. In a CCP structure, the number of anions per unit cell is 4. 2. **Determine the Number of Voids**: - In a CCP structure, there are two types of voids: - **Octahedral voids**: There are 4 octahedral voids per unit cell. - **Tetrahedral voids**: There are 8 tetrahedral voids per unit cell. 3. **Distribution of Cations**: - The cations `A` are distributed equally between the octahedral and tetrahedral voids. This means that half of the cations will occupy octahedral voids and the other half will occupy tetrahedral voids. 4. **Occupancy of Octahedral Voids**: - According to the problem, all octahedral voids are occupied. Since there are 4 octahedral voids, this means there are 4 cations `A` in the octahedral voids. 5. **Occupancy of Tetrahedral Voids**: - Since the cations are equally distributed, and there are 4 octahedral voids occupied by `A`, there will also be 4 cations `A` occupying the tetrahedral voids. 6. **Calculate Total Cations**: - The total number of cations `A` is the sum of those in octahedral and tetrahedral voids: \[ \text{Total } A = \text{Cations in octahedral voids} + \text{Cations in tetrahedral voids} = 4 + 4 = 8 \] 7. **Write the Formula**: - The formula for the ionic solid can be written as: \[ A_8B_4 \] 8. **Simplify the Formula**: - To simplify the formula, divide the subscripts by the greatest common divisor: \[ A_8B_4 \rightarrow A_2B \] ### Final Answer: The formula of the ionic solid is \( A_2B \).

To determine the formula of the ionic solid based on the arrangement of anions and cations, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Arrangement of Anions**: - The anions `B` are arranged in a cubic close-packed (CCP) structure. In a CCP structure, the number of anions per unit cell is 4. 2. **Determine the Number of Voids**: ...
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