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A compound formed by elements A and B cr...

A compound formed by elements `A` and `B` crystallises in a cubic structure where `A` atoms are present at the alternate corners of a cube and the `B` atoms are present at the alternate face centres.The formula of the compound is

A

`AB_(2)`

B

AB

C

`A_(3)B`

D

`A_(2)B_(3)`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the formula of the compound formed by elements A and B based on their positions in a cubic crystal structure. ### Step-by-Step Solution: 1. **Understanding the Structure**: - We have a cubic structure where A atoms are located at alternate corners and B atoms are at alternate face centers. 2. **Counting A Atoms**: - In a cube, there are 8 corners. Since A atoms are present at alternate corners, we will have 4 A atoms (1 at every alternate corner). - Each corner atom contributes \( \frac{1}{8} \) of an atom to the unit cell because each corner atom is shared by 8 adjacent cubes. - Therefore, the total contribution of A atoms in the unit cell is: \[ \text{Total A} = 4 \times \frac{1}{8} = \frac{4}{8} = \frac{1}{2} \] 3. **Counting B Atoms**: - There are 6 faces on a cube, and B atoms are present at alternate face centers. Thus, we have 2 B atoms (1 at every alternate face center). - Each face-centered atom contributes \( \frac{1}{2} \) of an atom to the unit cell because each face-centered atom is shared by 2 adjacent cubes. - Therefore, the total contribution of B atoms in the unit cell is: \[ \text{Total B} = 2 \times \frac{1}{2} = 1 \] 4. **Determining the Empirical Formula**: - Now we have: - Total A atoms = \( \frac{1}{2} \) - Total B atoms = \( 1 \) - To find the simplest whole number ratio, we can multiply both by 2: \[ A : B = \frac{1}{2} \times 2 : 1 \times 2 = 1 : 2 \] - Thus, the formula of the compound is \( AB_2 \). 5. **Final Answer**: - The formula of the compound formed by elements A and B is \( AB_2 \).

To solve the problem, we need to determine the formula of the compound formed by elements A and B based on their positions in a cubic crystal structure. ### Step-by-Step Solution: 1. **Understanding the Structure**: - We have a cubic structure where A atoms are located at alternate corners and B atoms are at alternate face centers. 2. **Counting A Atoms**: ...
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