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A solid crystal is composed of X, Y and ...

A solid crystal is composed of X, Y and Z atoms. Y atoms are occupying `50%` of octahedral voids, whereas X atoms are occupying the `100%` tetrahedral voids while Z atoms occupy CCP arrangement. The formula of the compound is:

A

`X_(8) Y_(2)Z_(4)`

B

`X_(5)Y_(10)Z_(8)`

C

`X_(4)YZ_(2)`

D

`X_(10)Y_(4)Z_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the formula of the compound composed of X, Y, and Z atoms, we will follow these steps: ### Step 1: Identify the arrangement of Z atoms - Z atoms occupy a close-packed (CCP) arrangement. In a CCP arrangement, there are 4 atoms per unit cell. **Hint:** Remember that in a CCP structure, the number of atoms per unit cell is always 4. ### Step 2: Determine the number of octahedral and tetrahedral voids - In a CCP arrangement, the number of octahedral voids is equal to the number of atoms, which is 4. - The number of tetrahedral voids in a CCP structure is double the number of atoms, which means there are 8 tetrahedral voids. **Hint:** For every atom in a CCP structure, there are specific ratios of octahedral and tetrahedral voids. ### Step 3: Calculate the number of Y atoms - According to the problem, Y atoms occupy 50% of the octahedral voids. Since there are 4 octahedral voids, Y atoms will occupy: \[ \text{Number of Y atoms} = 50\% \times 4 = 2 \] **Hint:** To find the number of Y atoms, calculate half of the total octahedral voids. ### Step 4: Calculate the number of X atoms - The problem states that X atoms occupy 100% of the tetrahedral voids. Since there are 8 tetrahedral voids, X atoms will occupy: \[ \text{Number of X atoms} = 100\% \times 8 = 8 \] **Hint:** When an atom occupies 100% of a void type, simply take the total number of those voids. ### Step 5: Write the empirical formula - Now we have: - X = 8 - Y = 2 - Z = 4 - The empirical formula can be written as: \[ \text{Formula} = X_8Y_2Z_4 \] - To simplify, we can divide all the subscripts by 2: \[ \text{Simplified Formula} = X_4YZ_2 \] **Hint:** Always simplify the empirical formula by dividing the subscripts by their greatest common divisor. ### Final Answer The formula of the compound is: \[ \text{Answer: } X_4Y_2Z \] ### Summary of Steps 1. Identify the number of Z atoms in CCP (4). 2. Determine the number of octahedral (4) and tetrahedral voids (8). 3. Calculate Y atoms (2 from 50% of 4 octahedral voids). 4. Calculate X atoms (8 from 100% of 8 tetrahedral voids). 5. Write and simplify the empirical formula (X4Y2Z).

To determine the formula of the compound composed of X, Y, and Z atoms, we will follow these steps: ### Step 1: Identify the arrangement of Z atoms - Z atoms occupy a close-packed (CCP) arrangement. In a CCP arrangement, there are 4 atoms per unit cell. **Hint:** Remember that in a CCP structure, the number of atoms per unit cell is always 4. ### Step 2: Determine the number of octahedral and tetrahedral voids ...
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