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The regular three dimensional arrangemen...

The regular three dimensional arrangement of points in a crystal is known as crystal lattice and the smallest repeating pattern in the lattice is called unit cell. The unit cells are characterised by the edge lengths a, b, c and the angles between them `alpha, beta and gamma` respectively. Based on this, there are seven crystal systems. In a cubic unit cell:
`a=b=c and alpha = beta=gamma=90^(@)` The number of points in simple, body centred and face centred cubic cells are 1,2 and 4 respectively In both the hcp and ccp of spheres, the number of tetrahedral voids per sphere is two while the octahedral voids is one.
In a face centred cubic cell, an atom at the face contributes to the unit cell

A

1 part

B

`1//2` part

C

`1//4` part

D

`1//8` part

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To solve the question regarding the contribution of an atom located at the face of a face-centered cubic (FCC) unit cell, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Face-Centered Cubic Structure**: - In a face-centered cubic (FCC) unit cell, atoms are located at each of the eight corners of the cube and at the center of each of the six faces. 2. **Counting the Atoms at the Corners**: - Each corner atom is shared by 8 adjacent unit cells. Therefore, the contribution of one corner atom to a single unit cell is \( \frac{1}{8} \). - Since there are 8 corners, the total contribution from the corner atoms is: \[ 8 \times \frac{1}{8} = 1 \text{ atom} \] 3. **Counting the Atoms at the Faces**: - Each face-centered atom is shared between 2 adjacent unit cells. Therefore, the contribution of one face-centered atom to a single unit cell is \( \frac{1}{2} \). - Since there are 6 faces, the total contribution from the face-centered atoms is: \[ 6 \times \frac{1}{2} = 3 \text{ atoms} \] 4. **Calculating Total Contribution**: - The total number of atoms in a face-centered cubic unit cell can be calculated by adding the contributions from the corner and face-centered atoms: \[ \text{Total atoms} = \text{Contribution from corners} + \text{Contribution from faces} = 1 + 3 = 4 \text{ atoms} \] 5. **Conclusion**: - Therefore, the contribution of an atom located at the face of a face-centered cubic cell to the unit cell is \( \frac{1}{2} \). ### Final Answer: The contribution of an atom at the face of a face-centered cubic cell to the unit cell is \( \frac{1}{2} \). ---

To solve the question regarding the contribution of an atom located at the face of a face-centered cubic (FCC) unit cell, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Face-Centered Cubic Structure**: - In a face-centered cubic (FCC) unit cell, atoms are located at each of the eight corners of the cube and at the center of each of the six faces. 2. **Counting the Atoms at the Corners**: ...
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The regular three dimensional arrangement of points in a crystal is known as crystal lattice and the smallest repeating pattern in the lattice is called unit cell. The unit cells are characterised by the edge lengths a, b, c and the angles between them alpha, beta and gamma respectively. Based on this, there are seven crystal systems. In a cubic unit cell: a=b=c and alpha = beta=gamma=90^(@) The number of points in simple, body centred and face centred cubic cells are 1,2 and 4 respectively In both the hcp and ccp of spheres, the number of tetrahedral voids per sphere is two while the octahedral voids is one. The C.N of cation occuppying an octahedral vois is:

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