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Select the correct statements (s)...

Select the correct statements (s)

A

Under high pressure, the co-ordination no. increases from `6:6 "to" 8:8`

B

Under high pressure, the co-ordination no.decreases from `8:8 " to " 6:6`

C

At high temperature, co-ordinate no. decreases

D

At 760 K, CsCl structure changes into NaCl structure

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the correct statements about coordination numbers under varying pressure and temperature, we will evaluate each statement one by one. ### Step-by-Step Solution: 1. **Evaluate Statement 1**: - Statement: "Under high pressure, the coordination number increases from 6 to 8." - Explanation: When pressure is increased, the particles in a crystal are forced closer together, leading to a more compact structure. This often results in an increase in the coordination number. Therefore, this statement is **correct**. 2. **Evaluate Statement 2**: - Statement: "Under high pressure, the coordination number decreases from 8 to 6." - Explanation: This statement contradicts the first statement. Since we established that coordination number increases with pressure, this statement is **incorrect**. 3. **Evaluate Statement 3**: - Statement: "At high temperature, the coordination number decreases." - Explanation: As temperature increases, the kinetic energy of the particles also increases, which can lead to a decrease in the coordination number as the particles may not stay as closely packed. Thus, this statement is **correct**. 4. **Evaluate Statement 4**: - Statement: "At 760 Kelvin, the cesium structure changes into NaCl structure." - Explanation: The cesium chloride structure has a coordination number of 8:8, while the NaCl structure has a coordination number of 6:6. As temperature increases, the coordination number can decrease, which aligns with the transition from cesium structure to NaCl structure at high temperatures. Therefore, this statement is **correct**. ### Conclusion: The correct statements are: - Statement 1: Correct - Statement 2: Incorrect - Statement 3: Correct - Statement 4: Correct Thus, the correct options are **Statement 1, Statement 3, and Statement 4**. ### Final Answer: The correct statements are 1, 3, and 4. ---
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