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Assertion (A) Alcohol is a weaker acid t...

Assertion (A) Alcohol is a weaker acid than water.
Reason (R) Sodium ethoxide may be prepared by the reaction of ethanol with aqueous NaOH.

A

Assertion and reason both are correct and reason is correct explanation of assertion.

B

Assertion and reasons both are wrong statements.

C

Assertion is correct statement but reasons is wrong statement.

D

Assertion is wrong statement but reason is correct statement

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that "Alcohol is a weaker acid than water." - **Explanation**: - Water (H2O) has two hydrogen atoms bonded to an oxygen atom, while alcohol (R-OH, where R is an alkyl group) has one hydrogen and one alkyl group. - The alkyl group exerts a +I (inductive) effect, which increases the electron density around the oxygen atom in alcohol. - This increased electron density makes the O-H bond in alcohol stronger compared to that in water. - As a result, it is more difficult for alcohol to donate a proton (H+) compared to water. - Therefore, water is a stronger acid than alcohol, making the assertion true. ### Step 2: Analyze the Reason The reason states that "Sodium ethoxide may be prepared by the reaction of ethanol with aqueous NaOH." - **Explanation**: - Sodium ethoxide (C2H5ONa) is actually prepared by the reaction of ethanol with sodium metal (Na), not with sodium hydroxide (NaOH). - The reaction with sodium metal produces sodium ethoxide and hydrogen gas (H2). - Therefore, the statement in the reason is incorrect. ### Conclusion - The assertion is correct: Alcohol is a weaker acid than water. - The reason is incorrect: Sodium ethoxide is not prepared by the reaction of ethanol with aqueous NaOH. Thus, the correct answer is that the assertion is true, but the reason is false. ### Final Answer Assertion (A) is true, and Reason (R) is false. ---

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that "Alcohol is a weaker acid than water." - **Explanation**: - Water (H2O) has two hydrogen atoms bonded to an oxygen atom, while alcohol (R-OH, where R is an alkyl group) has one hydrogen and one alkyl group. - The alkyl group exerts a +I (inductive) effect, which increases the electron density around the oxygen atom in alcohol. ...
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