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Dimethyl ether is completely soluble in ...

Dimethyl ether is completely soluble in water but diethyl ehter is soluble in water to small extent. Discuss.

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Dimethyl ether is completely soluble in water, but diethyl ether is soluble in water to a small extent.

(a) Explain why cleavage of phenyl ethers with HBr always produces phenol and alkyl bromides and not bromobenzene and alkanols. (b) Give reasons for the following: (i) The dipole moment of diethyl ether (1.18D) is lower than that of water (1.84D). (ii) The C-O-C bond angle in ethers is higher than H-O-H angle in water though oxygen is sp3 hybridized in both the cases. (iii) Dimethyl ether is completely miscible with water but diethyl ether is soluble in water to a small extent.

Knowledge Check

  • Diethyl ether is soluble in

    A
    Water
    B
    Dilute HCl
    C
    Conc. `H_(2)SO_(4)`
    D
    Conc. KOH
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