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State the product formed during the reac...

State the product formed during the reaction between sodium phenoxide and ethyl iodide on heating `:`

A

Phenetole

B

Ethyl phenyl alcohol

C

Phenone

D

None of these

Text Solution

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The correct Answer is:
To find the product formed during the reaction between sodium phenoxide and ethyl iodide upon heating, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are sodium phenoxide and ethyl iodide. Sodium phenoxide can be represented as C6H5O^-Na^+ and ethyl iodide as C2H5I. ### Step 2: Understand the Reaction Type This reaction is an example of the Williamson ether synthesis, which involves the reaction between a sodium alkoxide (sodium phenoxide) and a primary alkyl halide (ethyl iodide) to form an ether. ### Step 3: Mechanism of the Reaction In the Williamson synthesis: - The negatively charged oxygen of sodium phenoxide (C6H5O^-) acts as a nucleophile. - It attacks the electrophilic carbon of the ethyl iodide (C2H5I), which has a partial positive charge due to the presence of the iodine atom (a good leaving group). ### Step 4: Formation of the Ether As the nucleophile attacks, the bond between the carbon and iodine in ethyl iodide breaks, leading to the release of iodide ion (I^-). The result is the formation of an ether: - The product formed is ethyl phenyl ether, also known as phenetol (C6H5OCH2CH3). ### Step 5: Write the Balanced Reaction The balanced chemical equation for the reaction can be written as: \[ \text{C}_6\text{H}_5\text{O}^- \text{Na}^+ + \text{C}_2\text{H}_5\text{I} \rightarrow \text{C}_6\text{H}_5\text{O}\text{C}_2\text{H}_5 + \text{NaI} \] ### Conclusion Thus, the product formed during the reaction between sodium phenoxide and ethyl iodide on heating is ethyl phenyl ether (or phenetol). ---

To find the product formed during the reaction between sodium phenoxide and ethyl iodide upon heating, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are sodium phenoxide and ethyl iodide. Sodium phenoxide can be represented as C6H5O^-Na^+ and ethyl iodide as C2H5I. ### Step 2: Understand the Reaction Type This reaction is an example of the Williamson ether synthesis, which involves the reaction between a sodium alkoxide (sodium phenoxide) and a primary alkyl halide (ethyl iodide) to form an ether. ...
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