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Among the following ethers, which one wi...

Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated `HI`?

A

`CH_(3)-underset(CH_(3))underset(|)(CH)-CH_(2)-O-CH_(3)`

B

`CH_(3)-CH_(2)-CH_(2)-CH_(2)-O-CH_(3)`

C

`CH_(3)-CH_(2)-underset(CH_(3))underset(|)(CH)-O-CH_(3)`

D

`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which ether will produce methyl alcohol (methanol) upon treatment with hot concentrated HI, we need to analyze the ethers given in the options. ### Step-by-Step Solution: 1. **Identify the ethers**: We have four ethers to consider. Let's denote them as: - Option 1: CH3CH(CH3)CH2OCH3 - Option 2: CH3CH2CH2OCH3 - Option 3: CH3CH2CH(CH3)OCH3 - Option 4: (CH3)2C(CH3)OCH3 2. **Understand the reaction with HI**: Ethers react with hydrogen iodide (HI) to produce alcohols and alkyl iodides. The reaction typically involves cleavage of the ether bond (C-O) and formation of an alcohol and an alkyl halide. 3. **Analyze each ether**: - **Option 1**: CH3CH(CH3)CH2OCH3 - Upon reaction with HI, it can produce CH3OH (methyl alcohol) and CH3I (methyl iodide). - **Option 2**: CH3CH2CH2OCH3 - This will produce CH3OH and CH3CH2CH2I (propyl iodide). - **Option 3**: CH3CH2CH(CH3)OCH3 - This will produce CH3OH and CH3CH(CH3)I (isopropyl iodide). - **Option 4**: (CH3)2C(CH3)OCH3 - This will produce CH3OH and (CH3)2C(CH3)I (tert-butyl iodide). 4. **Determine which option produces methyl alcohol**: - From the analysis, **Option 1** is the only ether that directly produces methyl alcohol (CH3OH) upon reaction with HI. 5. **Conclusion**: Therefore, the ether that will produce methyl alcohol on treatment with hot concentrated HI is **Option 1**: CH3CH(CH3)CH2OCH3. ### Final Answer: **Option 1: CH3CH(CH3)CH2OCH3 produces methyl alcohol on treatment with hot concentrated HI.**

To determine which ether will produce methyl alcohol (methanol) upon treatment with hot concentrated HI, we need to analyze the ethers given in the options. ### Step-by-Step Solution: 1. **Identify the ethers**: We have four ethers to consider. Let's denote them as: - Option 1: CH3CH(CH3)CH2OCH3 - Option 2: CH3CH2CH2OCH3 - Option 3: CH3CH2CH(CH3)OCH3 ...
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