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Asssertion : 2-iodobutane on reacting wi...

Asssertion : 2-iodobutane on reacting with sodium ehtoxide. In ethanol gives but -2-ene as the major prodcut.
Reason : But-2-ene is more stable than but-1-ene.

A

If both assertion and reason are correct and reason is correct explanation for assertion.

B

If both assertion and reason are correct but reason is not correct for assertion.

C

If assertion is correct but reason is incorrect.

D

If both assertion and reason are incorrect.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided regarding the reaction of 2-iodobutane with sodium ethoxide in ethanol. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is 2-iodobutane (C4H9I), which has the structure: \[ CH_3-CH(I)-CH_2-CH_3 \] - The other reactant is sodium ethoxide (C2H5ONa). 2. **Understanding the Reaction Type**: - The reaction between an alkyl halide (2-iodobutane) and sodium ethoxide is a type of nucleophilic substitution reaction. This is often referred to as the Williamson ether synthesis. 3. **Mechanism of the Reaction**: - In this reaction, the ethoxide ion (C2H5O^-) acts as a nucleophile and attacks the carbon atom bonded to the iodine (the leaving group). - The iodine leaves as iodide ion (I^-), and an ether is formed. 4. **Formation of Ether**: - The reaction will produce an ether, specifically ethyl butyl ether: \[ CH_3-CH(OCH_2CH_3)-CH_2-CH_3 + NaI \] - This indicates that the assertion stating that but-2-ene is the major product is incorrect. 5. **Stability of Alkenes**: - The reason states that but-2-ene is more stable than but-1-ene. This is true because but-2-ene is a more substituted alkene compared to but-1-ene, which makes it more stable due to hyperconjugation and the inductive effect. 6. **Conclusion**: - Therefore, the assertion that 2-iodobutane gives but-2-ene as the major product is incorrect. - However, the reason that but-2-ene is more stable than but-1-ene is correct. ### Final Answer: - The assertion is **false**, and the reason is **true**.

To solve the question, we need to analyze the assertion and the reason provided regarding the reaction of 2-iodobutane with sodium ethoxide in ethanol. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is 2-iodobutane (C4H9I), which has the structure: \[ CH_3-CH(I)-CH_2-CH_3 ...
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