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Which of the following organic compound ...

Which of the following organic compound exhibits positive Fehling test as well as iodoform test?

A

propanol

B

Propanone

C

Butane-2-ol

D

Ethanal.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which organic compound exhibits both a positive Fehling test and a positive iodoform test, we need to analyze the characteristics of these tests and the given options. ### Step-by-Step Solution: 1. **Understanding the Fehling Test**: - The Fehling test is used to identify aldehydes. A positive Fehling test indicates the presence of a carbonyl group (C=O) in the form of an aldehyde (–CHO). Therefore, any compound that contains an aldehyde functional group will give a positive result in this test. 2. **Understanding the Iodoform Test**: - The iodoform test is used to identify methyl ketones (compounds with the structure CH3CO–) and some alcohols that can be oxidized to methyl ketones. A positive iodoform test indicates the presence of a methyl group adjacent to a carbonyl group (C=O). 3. **Analyzing the Options**: - **Option 1: Propanol (CH3-CH2-CH2OH)**: - Structure: This compound is an alcohol and does not contain a carbonyl group (C=O) or an aldehyde group (–CHO). - Conclusion: **Does not give a positive Fehling test or iodoform test.** - **Option 2: Propanone (CH3-CO-CH3)**: - Structure: This compound is a ketone. It contains a carbonyl group but does not have an aldehyde group. - Conclusion: **Gives a positive iodoform test but not a positive Fehling test.** - **Option 3: Butan-2-ol (CH3-CHOH-CH2-CH3)**: - Structure: This compound is an alcohol and does not contain a carbonyl group or an aldehyde group. - Conclusion: **Does not give a positive Fehling test or iodoform test.** - **Option 4: Ethanal (Acetaldehyde, CH3-CHO)**: - Structure: This compound contains an aldehyde group (–CHO) and also has a methyl group adjacent to a carbonyl group (C=O). - Conclusion: **Gives both a positive Fehling test and a positive iodoform test.** 4. **Final Answer**: - The organic compound that exhibits both a positive Fehling test and a positive iodoform test is **Option 4: Ethanal (Acetaldehyde)**.

To determine which organic compound exhibits both a positive Fehling test and a positive iodoform test, we need to analyze the characteristics of these tests and the given options. ### Step-by-Step Solution: 1. **Understanding the Fehling Test**: - The Fehling test is used to identify aldehydes. A positive Fehling test indicates the presence of a carbonyl group (C=O) in the form of an aldehyde (–CHO). Therefore, any compound that contains an aldehyde functional group will give a positive result in this test. 2. **Understanding the Iodoform Test**: ...
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