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CH(3)-CO OH overset(Br(2)//P)to(A) overs...

`CH_(3)-CO OH overset(Br_(2)//P)to(A) overset(NaCN)to(B) overset(HOH//H^(+))to(C)`
The product (C) will be

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the given reactions involving acetic acid (CH₃COOH) and identify the products formed at each stage. ### Step 1: Reaction of Acetic Acid with Bromine and Phosphorus The first step involves the reaction of acetic acid (CH₃COOH) with bromine (Br₂) in the presence of phosphorus (P). This is known as the Hell-Volhard-Zelinsky (HVZ) reaction, where an alpha hydrogen atom is replaced by a bromine atom. - **Reaction**: \[ \text{CH}_3\text{COOH} + \text{Br}_2/\text{P} \rightarrow \text{BrCH}_2\text{COOH} \] - **Product (A)**: The product formed is **alpha-bromoacetic acid (BrCH₂COOH)**. ### Step 2: Reaction of Alpha-Bromoacetic Acid with Sodium Cyanide In the second step, we treat the alpha-bromoacetic acid with sodium cyanide (NaCN). This reaction involves nucleophilic substitution, where the bromine atom is replaced by a cyanide group (CN). - **Reaction**: \[ \text{BrCH}_2\text{COOH} + \text{NaCN} \rightarrow \text{CH}_2\text{(CN)COOH} + \text{NaBr} \] - **Product (B)**: The product formed is **sinoacetic acid (CH₂(CN)COOH)**. ### Step 3: Hydrolysis of Sinoacetic Acid In the final step, we hydrolyze the sinoacetic acid using water (H₂O) in the presence of an acid (H⁺). This hydrolysis converts the nitrile group (CN) into a carboxylic acid (COOH). - **Reaction**: \[ \text{CH}_2\text{(CN)COOH} + \text{H}_2\text{O}/\text{H}^+ \rightarrow \text{CH}_2\text{(COOH)}_2 \] - **Product (C)**: The product formed is **malonic acid (CH₂(COOH)₂)**. ### Final Answer The product (C) will be **malonic acid (CH₂(COOH)₂)**. ---

To solve the problem step by step, we will analyze the given reactions involving acetic acid (CH₃COOH) and identify the products formed at each stage. ### Step 1: Reaction of Acetic Acid with Bromine and Phosphorus The first step involves the reaction of acetic acid (CH₃COOH) with bromine (Br₂) in the presence of phosphorus (P). This is known as the Hell-Volhard-Zelinsky (HVZ) reaction, where an alpha hydrogen atom is replaced by a bromine atom. - **Reaction**: \[ \text{CH}_3\text{COOH} + \text{Br}_2/\text{P} \rightarrow \text{BrCH}_2\text{COOH} ...
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