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The correct order of acidity for the fol...

The correct order of acidity for the following compounds is

A

`IgtIIgtIIIgtIV`

B

`IIIgtIgtIIgtIV`

C

`IIIgtIVgtIIgtI`

D

`IgtIIIgtIVgtII`

Text Solution

Verified by Experts

The correct Answer is:
B, C

(a) It is the correct order. It is explained on the basis of ortho effect and hydrogen bonding. Ortho effect is noticed in both (I) and (II). But acid (I) is stronger because intermolecular hydrogen bonding in the conjugate base of (I) is more than that of (II) since there are two OH groups present. Acid (II) is stranger acid than acid (I).
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