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Draw the structrue and name the product ...

Draw the structrue and name the product formed if the following alcohols are oxidized. Assume that an excess of oxidising agent is used.
(i) `CH_(3)CH_(2)CH_(2)CH_(2)OH`
(ii) 2-butenol
(iii) 2-methyl-1-propanol

Text Solution

Verified by Experts

The oxidation is generally carried with `KMnO_(4)` or `K_(2)Cr_(2)O_(7)` acidified with `H_(2)SO_(4)`.
(i) `underset("Butan-1-ol")(CH_(3)CH_(2)CH_(2)CH_(2)OH) overset("oxidation")(rarr) underset("Butanoic acid")(CH_(3)CH_(2)CH_(2)COOH)`
(ii) `underset("But-2-en-1-ol")(CH_(3)CH=CHCH_(2)OH) overset("oxidation")(rarr) underset("Ethanoic acid")(CH_(3)COOH)+underset("Ethanedioic acid")(HOOC COOH)`
(iii) `underset("2-Methylpropan-1-ol")(CH_(3)underset(CH_(3))underset(|)(CH)CH_(2)OH) overset("oxidation")(rarr) underset("2-Methylpropanoic acid")(CH_(3)underset(CH_(3))underset(|)(CH)COOH)`
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