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Explain the following observations: o-...

Explain the following observations:
o-and p-nitrophenols are more acidic than phenol.

Text Solution

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This is due to the reason that nitro `(-NO_(2))` group is electron withdrawing in nature and under its influence, release of `H^(+)` ion form phenol becomes easier as compared to phenol as such. For details, consult section 16.
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