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The correct set of quantum numbers (n, l...

The correct set of quantum numbers (n, l and m) respectively of the unpaired electron of chloine atom is

A

2,1,0

B

2,1,1

C

3,1,1

D

3,2,1

Text Solution

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The correct Answer is:
To determine the correct set of quantum numbers (n, l, and m) for the unpaired electron in a chlorine atom, we can follow these steps: ### Step 1: Determine the Electron Configuration of Chlorine The atomic number of chlorine (Cl) is 17, which means it has 17 electrons. The electron configuration for chlorine is: - 1s² 2s² 2p⁶ 3s² 3p⁵ ### Step 2: Identify the Last Electron In the electron configuration, the last unpaired electron is in the 3p orbital. The 3p subshell can hold a maximum of 6 electrons, but in chlorine, it has 5 electrons filled, leaving one unpaired electron. ### Step 3: Determine the Principal Quantum Number (n) The principal quantum number (n) indicates the energy level of the electron. For the unpaired electron in the 3p orbital: - n = 3 ### Step 4: Determine the Azimuthal Quantum Number (l) The azimuthal quantum number (l) defines the shape of the orbital. For p orbitals: - l = 1 ### Step 5: Determine the Magnetic Quantum Number (m) The magnetic quantum number (m) specifies the orientation of the orbital. For p orbitals, the possible values of m are -1, 0, and +1. The unpaired electron in the 3p subshell can occupy any of these orientations. In this case, we can choose: - m = +1 (this is one of the possible values for the unpaired electron) ### Summary of Quantum Numbers Thus, the correct set of quantum numbers (n, l, m) for the unpaired electron in a chlorine atom is: - n = 3 - l = 1 - m = +1 ### Final Answer The correct answer is (3, 1, +1). ---

To determine the correct set of quantum numbers (n, l, and m) for the unpaired electron in a chlorine atom, we can follow these steps: ### Step 1: Determine the Electron Configuration of Chlorine The atomic number of chlorine (Cl) is 17, which means it has 17 electrons. The electron configuration for chlorine is: - 1s² 2s² 2p⁶ 3s² 3p⁵ ### Step 2: Identify the Last Electron In the electron configuration, the last unpaired electron is in the 3p orbital. The 3p subshell can hold a maximum of 6 electrons, but in chlorine, it has 5 electrons filled, leaving one unpaired electron. ...
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Knowledge Check

  • The correct set of quantum numbers for the unpaired electron of chlorine atom is

    A
    n-2, l-1, m-0
    B
    n-2, l-1, m-1
    C
    n-3, l-1, m-1
    D
    n-3, l-0, m-0
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