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The wavelength of spectral line in Lyman...

The wavelength of spectral line in Lyman series for electron jumping back from 2nd orbit is

A

`1162 Å`

B

`1216 Å`

C

`1362 Å`

D

`1176 Å`

Text Solution

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The correct Answer is:
To find the wavelength of the spectral line in the Lyman series for an electron jumping from the second orbit, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Formula**: The formula to calculate the wavelength (λ) of spectral lines in the hydrogen atom is given by the Rydberg formula: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R_H \) is the Rydberg constant. 2. **Define Variables**: In the Lyman series, the electron transitions to the first orbit (n1 = 1). For the transition from the second orbit, we have: - \( n_1 = 1 \) - \( n_2 = 2 \) 3. **Substitute Values**: The Rydberg constant \( R_H \) is approximately \( 1.097 \times 10^7 \, \text{m}^{-1} \) (or \( 1.097 \times 10^5 \, \text{cm}^{-1} \)). Now substitute the values into the formula: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{1^2} - \frac{1}{2^2} \right) \] \[ \frac{1}{\lambda} = R_H \left( 1 - \frac{1}{4} \right) = R_H \left( \frac{3}{4} \right) \] 4. **Calculate**: Substitute \( R_H \): \[ \frac{1}{\lambda} = 1.097 \times 10^5 \, \text{cm}^{-1} \times \frac{3}{4} \] \[ \frac{1}{\lambda} = 1.097 \times 10^5 \times 0.75 = 8.2275 \times 10^4 \, \text{cm}^{-1} \] 5. **Find λ**: Now, take the reciprocal to find λ: \[ \lambda = \frac{1}{8.2275 \times 10^4} \approx 1.216 \times 10^{-5} \, \text{cm} \] 6. **Convert to Angstroms**: Since \( 1 \, \text{cm} = 10^8 \, \text{Å} \): \[ \lambda \approx 1.216 \times 10^{-5} \, \text{cm} \times 10^8 \, \text{Å/cm} = 1216 \, \text{Å} \] ### Final Answer: The wavelength of the spectral line in the Lyman series for an electron jumping from the second orbit is approximately **1216 Å**.

To find the wavelength of the spectral line in the Lyman series for an electron jumping from the second orbit, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Formula**: The formula to calculate the wavelength (λ) of spectral lines in the hydrogen atom is given by the Rydberg formula: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) ...
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