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Which one of the following arrangements ...

Which one of the following arrangements not truly represent the property indicated against it?

A

`Br_(2) lt Cl_(2) lt F_(2)` , electronegativity

B

`Br_(2) lt F_(2) lt Cl_(2)`, electron affinity

C

`Br_(2) lt Cl_(2) lt F_(2)`, bond energy

D

`Br_(2) lt Cl_(2) lt F_(2)`, oxidising power

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding which arrangement does not truly represent the indicated property, we will analyze each option step by step. ### Step-by-Step Solution: 1. **Understanding Electronegativity**: - Electronegativity is the tendency of an atom to attract shared electrons in a chemical bond. - In the case of halogens (F, Cl, Br), the electronegativity decreases as we move down the group from fluorine to bromine. - The correct order of electronegativity is: **F > Cl > Br**. - **Conclusion**: The arrangement for electronegativity is correct. 2. **Understanding Electron Affinity**: - Electron affinity refers to the energy change when an atom gains an electron. - Chlorine has a higher electron affinity than fluorine due to the smaller size of fluorine leading to electron-electron repulsion. - The correct order of electron affinity is: **Cl > F > Br**. - **Conclusion**: The arrangement for electron affinity is also correct. 3. **Understanding Bond Energy**: - Bond energy is the energy required to break a bond between two atoms. - The bond energy order for the halogens is influenced by the size and electron repulsion. - The correct order of bond energy is: **Cl2 > Br2 > F2**. - In this case, F2 has the lowest bond energy due to high electron repulsion in its small size. - **Conclusion**: The arrangement for bond energy is incorrect as stated in the question. 4. **Understanding Oxidizing Power**: - Oxidizing power is the ability of a substance to gain electrons. - The correct order of oxidizing power for halogens is: **F2 > Cl2 > Br2**. - **Conclusion**: The arrangement for oxidizing power is correct. ### Final Answer: The arrangement that does not truly represent the property indicated is the bond energy order: **F2 < Cl2 < Br2** (which should be **Cl2 > Br2 > F2**).
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