Home
Class 11
CHEMISTRY
According to Fajans'rules, the percentag...

According to Fajans'rules, the percentage of covalent character in an ionic compound increase if the cation is highly charged or small in size and the anion is large or cation has pseudoinert gas configuration. As a result of the increased covalent character, solubility in less polar solvent increases and the melting point decreases.
The correct order of increasing ionic character is

A

`BeCl_(2) lt MgCl_(2) lt CaCl_(2) lt BaCl_(2)`

B

`BeCl_(2) lt MgCl_(2) lt BaCl_(2) lt CaCl_(2)`

C

`BeCl_(2) lt BaCl_(2) lt MgCl_(2) lt CaCl_(2)`

D

`BaCl_(2) lt CaCl_(2) lt MgCl_(2) lt BeCl_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

The ionic character increase as
`BeCl_(2) lt MgCl_(2) lt CaCl_(2) lt BaCl_(2)`
Promotional Banner

Similar Questions

Explore conceptually related problems

According to Fajans'rules, the percentage of covalent character in an ionic compound increase if the cation is highly charged or small in size and the anion is large or cation has pseudoinert gas configuration. As a result of the increased covalent character, solubility in less polar solvent increases and the melting point decreases. Which of the following has highest melting point?

According to Fajans'rules, the percentage of covalent character in an ionic compound increase if the cation is highly charged or small in size and the anion is large or cation has pseudoinert gas configuration. As a result of the increased covalent character, solubility in less polar solvent increases and the melting point decreases. Which of the following has the lowest melting point?

Which is correct in increasing order of ionic character ?

Which of the following has been arranged order of increasing covalent character ? .

Metal hydrides are ionic, covalent or molecular in nature. Among LiH, NaH, KH, RbH, CsH the correct order of increasing ionic character is

Metal hydrides are ionic, covalent or molecular in nature. Among LiH, NaH, KH, RbH, CsH the correct order of increasing ionic character is

in an ionic bond the cation tends to polarise the electron cloud of the anion by pulling electron density towards itself This causes development of covalent character in the ionic bond because the electron density gets localised in between the nuclei The tendency of the cation to bring about the polarisation of the anion is expressed as its polasising power The ability of ion to undergo polarisation is called its polarisability The polarising power of a cation or an anion is decided on the basis of F ajans' rules as follows . (i) The smaller the cation, the higher is its polarising power (ii) Cations with pseudo-noble gas configuration (ns^(2)np^(6)nd^(10)) have relatively high polarising power than those with noble gas configuration (ns^(2) np^(6)) (iii) The larger the size of the anion, the higher is its polarisability Choose the correct order of polarisability for the following I^(Θ),Br^(Θ),CI^(Θ)F^(Θ) .

in an ionic bond the cation tends to polarise the electron cloud of the anion by pulling electron density towards itself This causes development of covalent character in the ionic bond because the electron density gets localised in between the nuclei The tendency of the cation to bring about the polarisation of the anion is expressed as its polasising power The ability of ion to undergo polarisation is called its polarisability The polarising power of a cation or an anion is decided on the basis of F ajans' rules as follows . (i) The smaller the cation, the higher is its polarising power (ii) Cations with pseudo-noble gas configuration (ns^(2)np^(6)nd^(10)) have relatively high polarising power than those with noble gas configuration (ns^(2) np^(6)) (iii) The larger the size of the anion, the higher is its polarisability The ionic conductance of which of the following is the highest ? .

in an ionic bond the cation tends to polarise the electron cloud of the anion by pulling electron density towards itself This causes development of covalent character in the ionic bond because the electron density gets localised in between the nuclei The tendency of the cation to bring about the polarisation of the anion is expressed as its polasising power The ability of ion to undergo polarisation is called its polarisability The polarising power of a cation or an anion is decided on the basis of F ajans' rules as follows . (i) The smaller the cation, the higher is its polarising power (ii) Cations with pseudo-noble gas configuration (ns^(2)np^(6)nd^(10)) have relatively high polarising power than those with noble gas configuration (ns^(2) np^(6)) (iii) The larger the size of the anion, the higher is its polarisability Arranfe of the following species in dereasing order of polarising powers Ag^(o+),TI^(o+),Na^(o+) .

In which of the following options order of arrangement does not agree with the variatioin of property indicated against it? Thinking process. i) The ionic size increases as the positive charge on the cation decreases or the negative charge on the anion increases. ii) First ionisation enthalpy increases from left to right in the periodic table. iii) Electron gain enthalpy increases as the electronegativity of the atom increases. iv) The metallic character increases as the size of the metal atom increases.