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Assertion: Oxides are more ionic than co...

Assertion: Oxides are more ionic than corresponding sulphides.
Reason: Oxygen has higher electron affinity than sulphur.

A

Both A and B true and R is the correct explanation A

B

Both A and R are true but R is not a correct explanation of A

C

A is true but R is false

D

A is false but R is true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "Oxides are more ionic than corresponding sulphides." - To evaluate this, we need to consider the nature of ionic compounds. Ionic character in compounds is influenced by the difference in electronegativity between the two elements involved. 2. **Electronegativity Comparison**: - Oxygen (O) has a higher electronegativity (approximately 3.44 on the Pauling scale) compared to Sulfur (S), which has an electronegativity of about 2.58. - A higher electronegativity difference between the metal and the non-metal leads to a stronger ionic bond. Since oxygen is more electronegative than sulfur, oxides will generally exhibit more ionic character than corresponding sulphides. 3. **Conclusion on Assertion**: - Therefore, the assertion that "Oxides are more ionic than corresponding sulphides" is **True**. 4. **Understanding the Reason**: - The reason states that "Oxygen has higher electron affinity than sulphur." - Electron affinity is the energy change when an electron is added to a neutral atom. 5. **Electron Affinity Comparison**: - In fact, the electron affinity of sulfur is greater than that of oxygen. This is due to the smaller size of oxygen, which leads to increased inter-electronic repulsion when an additional electron is added. - Thus, the statement that "Oxygen has higher electron affinity than sulphur" is **False**. 6. **Final Evaluation**: - Since the assertion is true and the reason is false, we conclude that the correct answer is that the assertion is true while the reason is false. ### Final Answer: - **Assertion**: True - **Reason**: False - **Correct Option**: C (Assertion is true, Reason is false)
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