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First ionisation potential for copper is...

First ionisation potential for copper is higher than that for potassium. The second ionisation potential of copper is

A

Equal to the 2nd ionisation potential of potasium

B

more then the 2 nd ionisation potential of potassium

C

less than the 2nd ionisation potential of potassium

D

less than the 2nd ionisation potential of potassium

Text Solution

Verified by Experts

`Cu:(Z=29) : 1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)4s^(1)3d^(10)`
`K(Z=19): 1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)4s^(1)`
`Cu^(+): 1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)3d^(10)`
`K^(+) : 1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)`
Clearly second ionisation energy of K will be more than Cu because in case of K the second electron is to be removed from fully filled 3rd shell.
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