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For the reaction 4A +B rarr 2C+2D whic...

For the reaction
`4A +B rarr 2C+2D` which of the following statements is not correct:

A

Rate of dissapearance of B is `1//4` th of rate of dissappearance of A

B

Rate of formation of C is `1//2` the rate of consumption of A

C

Rate of apperance of D is `1//2` the rate of dissappearance of B

D

Rate of formation of C and D are equal

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is not correct for the reaction \(4A + B \rightarrow 2C + 2D\), we will analyze the rates of disappearance and appearance of the reactants and products involved in the reaction. ### Step-by-Step Solution: 1. **Identify the Reaction Stoichiometry**: The balanced equation is: \[ 4A + B \rightarrow 2C + 2D \] From this equation, we can see the stoichiometric coefficients: 4 for A, 1 for B, 2 for C, and 2 for D. 2. **Write the Rate Expressions**: The rate of the reaction can be expressed in terms of the change in concentration of the reactants and products: - Rate of disappearance of A: \[ -\frac{1}{4} \frac{d[A]}{dt} \] - Rate of disappearance of B: \[ -\frac{1}{1} \frac{d[B]}{dt} \] - Rate of appearance of C: \[ \frac{1}{2} \frac{d[C]}{dt} \] - Rate of appearance of D: \[ \frac{1}{2} \frac{d[D]}{dt} \] 3. **Analyze Each Statement**: - **Statement 1**: "The rate of disappearance of B is \( \frac{1}{4} \) the rate of appearance of A." - This statement is **correct** because the rate of disappearance of B is indeed \( \frac{1}{4} \) of the rate of disappearance of A based on their stoichiometric coefficients. - **Statement 2**: "The rate of formation of C is \( \frac{1}{2} \) the rate of consumption of A." - This statement is also **correct** because the rate of formation of C is \( \frac{1}{2} \) the rate of consumption of A based on their stoichiometric coefficients. - **Statement 3**: "The rate of appearance of B is \( \frac{1}{2} \) the rate of disappearance of B." - This statement is **incorrect**. The rate of appearance of B cannot be compared to its own rate of disappearance in this way. The appearance of B is not applicable since B is a reactant and is consumed, not produced. - **Statement 4**: "The rate of formation of C and D are equal." - This statement is **correct** because both C and D are produced in equal amounts (2 moles each) according to the balanced equation. 4. **Conclusion**: The statement that is not correct is **Statement 3**.

To determine which statement is not correct for the reaction \(4A + B \rightarrow 2C + 2D\), we will analyze the rates of disappearance and appearance of the reactants and products involved in the reaction. ### Step-by-Step Solution: 1. **Identify the Reaction Stoichiometry**: The balanced equation is: \[ 4A + B \rightarrow 2C + 2D ...
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