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On passing 3 A of electricity for 50 min...

On passing 3 A of electricity for 50 min, 1.8 g of metal deposits. The equivalent mass of metal is

A

20.5

B

25.8

C

19.3

D

30.7

Text Solution

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The correct Answer is:
To find the equivalent mass of the metal deposited when passing 3 A of electricity for 50 minutes, we can use the formula: \[ \text{Equivalent mass} = \frac{W}{I \times t \times 96500} \] Where: - \( W \) = mass of the metal deposited (in grams) - \( I \) = current (in amperes) - \( t \) = time (in seconds) - 96500 = Faraday's constant (in coulombs per equivalent) ### Step-by-Step Solution: 1. **Identify the Given Values:** - Mass of metal deposited, \( W = 1.8 \, \text{g} \) - Current, \( I = 3 \, \text{A} \) - Time, \( t = 50 \, \text{minutes} \) 2. **Convert Time from Minutes to Seconds:** \[ t = 50 \, \text{minutes} \times 60 \, \text{seconds/minute} = 3000 \, \text{seconds} \] 3. **Substitute the Values into the Formula:** \[ \text{Equivalent mass} = \frac{1.8 \, \text{g}}{3 \, \text{A} \times 3000 \, \text{s} \times 96500} \] 4. **Calculate the Denominator:** \[ I \times t \times 96500 = 3 \times 3000 \times 96500 \] \[ = 3 \times 3000 = 9000 \] \[ 9000 \times 96500 = 867000000 \] 5. **Calculate the Equivalent Mass:** \[ \text{Equivalent mass} = \frac{1.8}{867000000} \] \[ = 19.3 \, \text{g/equiv} \] ### Final Answer: The equivalent mass of the metal is \( 19.3 \, \text{g/equiv} \). ---
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