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At 298K the resistance of a 0.5N NaOH so...

At 298K the resistance of a 0.5N NaOH solution is 35.0 ohm. The cell constant is 0.503 `cm^(-1)` the electrical conductivity of the solution is

A

`1.437xx10^(-2)ohm ^(-1)cm^(-1)`

B

`1.473ohm^(-1)cm^(-1)`

C

`1.06ohm^(-1)cm^(-1)`

D

`3.5ohm^(-1)cm^(-1)`.

Text Solution

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The correct Answer is:
To find the electrical conductivity of the 0.5N NaOH solution, we can use the relationship between conductivity (κ), resistance (R), and cell constant (G). The formula we will use is: \[ \kappa = G \cdot \frac{1}{R} \] where: - \( \kappa \) is the electrical conductivity, - \( G \) is the cell constant, - \( R \) is the resistance. ### Step-by-Step Solution: 1. **Identify the given values**: - Resistance, \( R = 35.0 \, \Omega \) - Cell constant, \( G = 0.503 \, \text{cm}^{-1} \) 2. **Calculate the conductance (G)**: Conductance is the reciprocal of resistance: \[ G = \frac{1}{R} = \frac{1}{35.0 \, \Omega} \] 3. **Calculate the conductance**: \[ G = \frac{1}{35.0} \approx 0.02857 \, \text{S} \, \text{(Siemens)} \] 4. **Calculate the electrical conductivity (κ)**: Now, substitute the values of conductance and cell constant into the conductivity formula: \[ \kappa = G \cdot \frac{1}{R} = 0.503 \, \text{cm}^{-1} \cdot 0.02857 \, \text{S} \] 5. **Perform the calculation**: \[ \kappa = 0.503 \cdot 0.02857 \approx 0.01437 \, \text{S/cm} \] 6. **Convert to appropriate units**: Since \( 1 \, \text{S/cm} = 10^2 \, \text{mS/cm} \), we can express it as: \[ \kappa \approx 1.437 \times 10^{-2} \, \text{S/cm} \] ### Final Answer: The electrical conductivity of the 0.5N NaOH solution is approximately \( 1.437 \times 10^{-2} \, \text{S/cm} \).

To find the electrical conductivity of the 0.5N NaOH solution, we can use the relationship between conductivity (κ), resistance (R), and cell constant (G). The formula we will use is: \[ \kappa = G \cdot \frac{1}{R} \] where: - \( \kappa \) is the electrical conductivity, ...
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