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Specific conductance of 0.1M nitric acid...

Specific conductance of 0.1M nitric acid is
`6.3xx10^(-2)ohm^(-1)cm^(-1)`. The molar conductance of the
solution is:

A

`630ohm^(-1)cm^(2)"mol"^(-1)`

B

`315ohm^(-1)cm^(2)"mol"^(-1)`

C

`100ohm^(-1)cm^(2)"mol"^(-1)`

D

`6.300ohm^(-1)cm^(2)"mol"^(-1)`

Text Solution

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The correct Answer is:
To find the molar conductance of a 0.1 M nitric acid solution given its specific conductance, we can follow these steps: ### Step 1: Understand the relationship between specific conductance and molar conductance Molar conductance (Λ) can be calculated from specific conductance (κ) using the formula: \[ \Lambda = \frac{\kappa \times 1000}{C} \] where: - \( \Lambda \) is the molar conductance in ohm\(^{-1}\)cm\(^2\)mol\(^{-1}\), - \( \kappa \) is the specific conductance in ohm\(^{-1}\)cm\(^{-1}\), - \( C \) is the concentration in mol/L. ### Step 2: Plug in the values We are given: - Specific conductance \( \kappa = 6.3 \times 10^{-2} \) ohm\(^{-1}\)cm\(^{-1}\) - Concentration \( C = 0.1 \) mol/L Now substituting these values into the formula: \[ \Lambda = \frac{6.3 \times 10^{-2} \, \text{ohm}^{-1}\text{cm}^{-1} \times 1000 \, \text{cm}^3/\text{L}}{0.1 \, \text{mol/L}} \] ### Step 3: Calculate the numerator Calculating the numerator: \[ 6.3 \times 10^{-2} \times 1000 = 63 \, \text{ohm}^{-1}\text{cm}^{-1} \] ### Step 4: Divide by the concentration Now, we divide by the concentration: \[ \Lambda = \frac{63 \, \text{ohm}^{-1}\text{cm}^{-1}}{0.1 \, \text{mol/L}} = 630 \, \text{ohm}^{-1}\text{cm}^{2}\text{mol}^{-1} \] ### Step 5: Write the final answer Thus, the molar conductance of the 0.1 M nitric acid solution is: \[ \Lambda = 630 \, \text{ohm}^{-1}\text{cm}^{2}\text{mol}^{-1} \]

To find the molar conductance of a 0.1 M nitric acid solution given its specific conductance, we can follow these steps: ### Step 1: Understand the relationship between specific conductance and molar conductance Molar conductance (Λ) can be calculated from specific conductance (κ) using the formula: \[ \Lambda = \frac{\kappa \times 1000}{C} \] where: ...
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