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The volume of H(2) gas at NTP obtained b...

The volume of `H_(2)` gas at NTP obtained by passing 4 amperes
through acidified `H_(2)O` for 30 minutes is

A

0.836L

B

0.0432L

C

0.1672L

D

5.6L

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of finding the volume of \( H_2 \) gas at NTP obtained by passing 4 amperes through acidified \( H_2O \) for 30 minutes, we can follow these steps: ### Step 1: Calculate the total charge (Q) passed The formula for charge is given by: \[ Q = I \times t \] where: - \( I \) is the current in amperes (A) - \( t \) is the time in seconds (s) Given: - \( I = 4 \, A \) - \( t = 30 \, \text{minutes} = 30 \times 60 \, \text{seconds} = 1800 \, s \) Now, substituting the values: \[ Q = 4 \, A \times 1800 \, s = 7200 \, C \] ### Step 2: Relate charge to moles of \( H_2 \) From electrolysis, we know that: - 2 moles of electrons produce 1 mole of \( H_2 \). - 1 mole of electrons corresponds to 1 Faraday of charge, which is approximately \( 96500 \, C \). Thus, for 2 moles of electrons: \[ \text{Charge for 1 mole of } H_2 = 2 \times 96500 \, C = 193000 \, C \] ### Step 3: Calculate the moles of \( H_2 \) produced Using the total charge calculated: \[ \text{Moles of } H_2 = \frac{Q}{\text{Charge for 1 mole of } H_2} = \frac{7200 \, C}{193000 \, C} \approx 0.0373 \, \text{moles} \] ### Step 4: Calculate the volume of \( H_2 \) at NTP At Normal Temperature and Pressure (NTP), 1 mole of any ideal gas occupies 22.4 liters. Therefore, the volume of \( H_2 \) produced can be calculated as: \[ \text{Volume of } H_2 = \text{Moles of } H_2 \times 22.4 \, \text{L/mol} = 0.0373 \, \text{moles} \times 22.4 \, \text{L/mol} \approx 0.836 \, \text{L} \] ### Final Answer The volume of \( H_2 \) gas at NTP obtained is approximately \( 0.836 \, \text{liters} \). ---

To solve the problem of finding the volume of \( H_2 \) gas at NTP obtained by passing 4 amperes through acidified \( H_2O \) for 30 minutes, we can follow these steps: ### Step 1: Calculate the total charge (Q) passed The formula for charge is given by: \[ Q = I \times t \] where: ...
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