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Ethyl acetate reacts with NH2NHCONH2 to ...

Ethyl acetate reacts with `NH_2NHCONH_2` to form

A

`CH_3 CONHCONHNH_2`

B

`CH_3CON(NH_2) CONH_2`

C

`CH_3 CONHNHCONH_2`

D

`CH_3 CH_2 NHNHCONH_2`

Text Solution

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The correct Answer is:
To solve the problem of how ethyl acetate reacts with hydrazinecarboxamide (NH2-NHCO-NH2), we can break down the reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: - Ethyl acetate has the structure: CH3COOCH2CH3. - Hydrazinecarboxamide is NH2-NHCO-NH2. 2. **Nucleophilic Attack**: - The nitrogen atom in hydrazinecarboxamide (NH2-NHCO-NH2) acts as a nucleophile. The lone pair of electrons on the nitrogen will attack the carbonyl carbon (C=O) of ethyl acetate. - This results in the formation of a tetrahedral intermediate. 3. **Formation of the Intermediate**: - The intermediate formed will have the structure: CH3C(OH)(NH2-NHCO-NH2)OCH2CH3. - Here, the carbonyl oxygen becomes negatively charged, and the nitrogen forms a bond with the carbonyl carbon. 4. **Proton Transfer**: - A proton (H+) from the nitrogen will be transferred to the negatively charged oxygen, leading to the stabilization of the intermediate. 5. **Elimination of Water**: - The intermediate can lose a water molecule (H2O) as a result of the rearrangement, leading to the formation of a more stable product. 6. **Final Product**: - The final product formed from this reaction is CH3CONHNHCO-NH2. - This compound is known as a hydrazone derivative. ### Final Answer: The product formed when ethyl acetate reacts with NH2-NHCO-NH2 is CH3CONHNHCO-NH2.

To solve the problem of how ethyl acetate reacts with hydrazinecarboxamide (NH2-NHCO-NH2), we can break down the reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: - Ethyl acetate has the structure: CH3COOCH2CH3. - Hydrazinecarboxamide is NH2-NHCO-NH2. ...
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KVPY PREVIOUS YEAR-QUESTION PAPER 2013-PART-I ( CHEMISTRY)
  1. Among the following, the set of isoelectronic ions is

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  2. For a zero-order reaction with rate constant k, the slope of the plot ...

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  3. The compound which reacts with excess bromine to produce 2, 4, 6-tribr...

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  4. Ethyl acetate reacts with NH2NHCONH2 to form

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  5. The variation of solubility of four different gases (G1, G2, etc.) in ...

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  6. For the reaction, A iff n B the concentration of A decreases from 0.0...

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  7. The reaction of ethyl methyl ketone with Cl(2)//"excess" OH^(-) gives ...

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  8. The compound that readily tautomerizes is

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  9. Hydrolysis of BCl3 gives X which on treatment with sodium carbonate pr...

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  10. The numbers of lone pair(s) on Xe in XeF2 and XeF4 are, respectively

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  11. The entropy change in the isothermal reversible expansion of 2 moles o...

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  12. D-Glucose upon treatment with bromine-water gives

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  13. In the structure of borax, the numbers of boron atoms and B-O-B units,...

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  14. The number of peptide bonds in the compound is

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  15. For the isothermal reversible expansion of an ideal gas

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  16. If the angle of incidence of X-ray of wavelength 3Å which produces a s...

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  17. The number of ions produced in water by dissolution of the complex hav...

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  18. The spin-only magnetic moment of [Fe(NH(3))(6)]^(3+) and [FeF(6)]^(3-)...

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  19. The order of ,SN 1 reactivity in aqueous acetic acid solution for the ...

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  20. An ionic compound is formed between a metal M and a non-metal Y. If M ...

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