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The compound that readily tautomerizes i...

The compound that readily tautomerizes is

A

`CH_3 COCH_2 CO_2 C_2H_5`

B

`CH_3 COCH_2 CH_2 CH_3`

C

`CH_3 CO CH_2 CH_2 CH_3`

D

`(CH_3)_3 C COC(CH_3)_3`

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The correct Answer is:
To determine which compound readily tautomerizes, we need to understand the concept of tautomerism. Tautomerism is a chemical phenomenon where a compound exists in two interconvertible forms, typically involving the migration of a hydrogen atom and a shift in a double bond. The most common example is the keto-enol tautomerism. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to analyze the given options to identify which one has the potential for tautomerism. The options typically include compounds with carbonyl groups (C=O) and active methylene groups. 2. **Look for Active Methylene Groups**: An active methylene group is a carbon atom adjacent to a carbonyl group that has hydrogen atoms attached. This group can easily lose a hydrogen atom to form an enol or an enolate ion, facilitating tautomerism. 3. **Analyze the First Option**: The first compound mentioned has a carbonyl group and an active methylene group. This compound can readily undergo tautomerization because the hydrogen from the methylene group can migrate to the carbonyl oxygen, forming an enol. 4. **Analyze the Second Option**: The second compound lacks the necessary active methylene group adjacent to the carbonyl. Therefore, it will not tautomerize readily. 5. **Analyze the Third Option**: The third compound also does not have an active methylene group next to the carbonyl. The absence of a hydrogen atom on the carbon adjacent to the carbonyl means it cannot undergo tautomerization. 6. **Conclusion**: Based on the analysis, the first compound is the one that readily tautomerizes due to the presence of an active methylene group. ### Final Answer: The compound that readily tautomerizes is the first option.

To determine which compound readily tautomerizes, we need to understand the concept of tautomerism. Tautomerism is a chemical phenomenon where a compound exists in two interconvertible forms, typically involving the migration of a hydrogen atom and a shift in a double bond. The most common example is the keto-enol tautomerism. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to analyze the given options to identify which one has the potential for tautomerism. The options typically include compounds with carbonyl groups (C=O) and active methylene groups. 2. **Look for Active Methylene Groups**: ...
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Identify the compound that exhibits tautomerism

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Identify the compound that exhibits tautomerism.

KVPY PREVIOUS YEAR-QUESTION PAPER 2013-PART-I ( CHEMISTRY)
  1. Among the following, the set of isoelectronic ions is

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  2. For a zero-order reaction with rate constant k, the slope of the plot ...

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  3. The compound which reacts with excess bromine to produce 2, 4, 6-tribr...

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  4. Ethyl acetate reacts with NH2NHCONH2 to form

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  5. The variation of solubility of four different gases (G1, G2, etc.) in ...

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  6. For the reaction, A iff n B the concentration of A decreases from 0.0...

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  7. The reaction of ethyl methyl ketone with Cl(2)//"excess" OH^(-) gives ...

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  8. The compound that readily tautomerizes is

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  9. Hydrolysis of BCl3 gives X which on treatment with sodium carbonate pr...

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  10. The numbers of lone pair(s) on Xe in XeF2 and XeF4 are, respectively

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  11. The entropy change in the isothermal reversible expansion of 2 moles o...

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  12. D-Glucose upon treatment with bromine-water gives

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  13. In the structure of borax, the numbers of boron atoms and B-O-B units,...

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  14. The number of peptide bonds in the compound is

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  15. For the isothermal reversible expansion of an ideal gas

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  16. If the angle of incidence of X-ray of wavelength 3Å which produces a s...

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  17. The number of ions produced in water by dissolution of the complex hav...

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  18. The spin-only magnetic moment of [Fe(NH(3))(6)]^(3+) and [FeF(6)]^(3-)...

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  19. The order of ,SN 1 reactivity in aqueous acetic acid solution for the ...

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  20. An ionic compound is formed between a metal M and a non-metal Y. If M ...

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