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Does the experimental voume versus tempe...

Does the experimental voume versus temperature relation at constant pressure deviates from which is given by Charles, law, if so, under what condition?

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Vapour pessure of a liquid or a solution is the pressure exerted by the vapour in equilibrium with the liquid or solution at a particular temperature. It depends upon the nature of the liquid and temperature. It depends upon the nature of the liquid and temperature. According to Raoult's law in a solution, the vapour pressure of a component at a given temperature is equal to the mole fraction of that component in solution multiplied by the vapour pressure of that component in hte pue state. this solution in which each component obeys Raoult's law are called ideal solutions. there are two types of non ideal solutions, showing positive deviations and negative deviations from ideal behaviour. If liquid A and B form ideal solution, then

Gibbs Helmholtz equation relates the enthalpy, entropy and free energy change of the process at constant pressure and temperature as DeltaG=DeltaH-TDeltaS " (at constant P, T)" In General the magnitude of DeltaH does not change much with the change in temperature but the terms TDeltaS changes appreciably. Hence in some process spontaneity is very much dependent on temperature and such processes are generally known as entropy driven process. When CaCO_(3) is heated to a high temperature it decomposes into CaO and CO_(2) , however it is quite stable at room temperature. It can be explained by the fact that

Gibbs Helmholtz equation relates the enthalpy, entropy and free energy change of the process at constant pressure and temperature as DeltaG=DeltaH-TDeltaS " (at constant P, T)" In General the magnitude of DeltaH does not change much with the change in temperature but the terms TDeltaS changes appreciably. Hence in some process spontaneity is very much dependent on temperature and such processes are generally known as entropy driven process. For the reaction at 298 K, A_(2)B_(4)rarr2AB_(2) DeltaH=2" kJ" and DeltaS = 20 J/K at constant P and T, the reaction will be

Gibbs Helmholtz equation relates the enthalpy, entropy and free energy change of the process at constant pressure and temperature as DeltaG=DeltaH-TDeltaS " (at constant P, T)" In General the magnitude of DeltaH does not change much with the change in temperature but the terms TDeltaS changes appreciably. Hence in some process spontaneity is very much dependent on temperature and such processes are generally known as entropy driven process. The Dissolution of CaCl_(2).6H_(2)O in a large volume of water is endothermic to the extent of 3.5 kcal "mol"^(-1) and DeltaH for the reaction is -23.2 kcal "mol"^(-1) . CaCl_(2)(s)+6H_(2)O(l)rarrCaCl_(2).6H_(2)O(s) Select the correct statement :

Which of the following does not show positive deviation from Raoult's law ?

Which one of the following relationships when graphed does not give a straight line for helium gas? I. K.E. and T at constant pressure and volume II. P v/s V at constant temperature for a constant mass III. V v/s 1/T at constant pressure for a constant mass

The locus of a point which moves so that the difference of the squares of its distance from two given points is constant, is a

JBD PUBLICATION-Behaviour of Perfect Gases and Kinetic Theory of Gases-EXERCISE
  1. Fill in the blanks: The man free path of a molecule of a gas at S.T.P...

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  2. What is the temperature, at which molecular motion ceases?

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  3. Does the experimental voume versus temperature relation at constant pr...

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  4. On what factors does the average kinetic energy of gas molecules depen...

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  5. What is the importance of a absolute scale of temperature?

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  6. At 273 K, watr solidifies into ice. What happens to the kinetic energy...

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  7. A box contains equal number of molecules of hydrogen and oxygen. If th...

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  8. Prove that kinetic energy of gas is proportional to absolute temperatu...

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  9. Name the various speeds which are used to characterise the motion of a...

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  10. A gas behaves like an ideal gas at :

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  11. Given sample of 1 c.c. of hydrogen and 1 cm^3 of oxygen both at NTP. W...

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  12. Does Boye's law hold true for real gases even for high pressure and lo...

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  13. Define critical temperature.

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  14. Why don't we consider the changes in gravitational potential energy of...

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  15. What is the difference between vapour and gas?

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  16. A box contains equal number of molecules of hydrogen and oxygen. If th...

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  17. What is an ideal gas ?

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  18. Give the kinetic Interpretatin of Temperature.

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  19. What is meant by degrees of freedom? Find degrees of freedom for mono ...

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  20. A gas behaves like an ideal gas at :

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