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Explain briefly homogeneous catalysis....

Explain briefly homogeneous catalysis.

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Homogeneous catalysis: When the reactants and the catalyst are in the same phase (i.e., liquid or gas), the process is said to be homogeneous catalysis. The following are some of the examples of homogeneous catalysis :
Oxidation of sulphur dioxide into sulphur dioxide with dioxygen in the presence of oxides of nitrogen as the catalyst in the lead chamber process.
`2SO_2 (g) + O_2 (g) overset(NO(g))to 2SO_3 (g)`
The reactants, sulphur dioxide and oxygen, and the catalyst, nitric oxide, are all in the same phase
(ii) Hydrolysis of methyl acetate is catalysed by `H^+` ions furnished by hydrochloric acid.
`CH_3 COO CH_3 (l) + H_2 O (l) overset(HCl (l))to CH_3 COOH (aq) + CH_3 OH (aq)`
Both the reactants and the catalyst are in the same phase.
(iii) Hydrolysis of sugar is catalysed by `H^+` ions furnished by sulphuric acid.
`underset("Solution")(C_(12)H_(22) O_(11)(aq)) + H_2 O (l) overset(H_2 SO_4 (l))to underset("Solution")ubrace(underset("Glucose")(C_(6) H_(12)O_6 (aq)) + underset("Fructose")(C_6 H_(12) O_6(aq)))`
Both the reactants and the catalyst are in the same phase.
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BETTER CHOICE PUBLICATION-SURFACE CHEMISTRY -Question Bank
  1. What is homogeneous and heterogeneous catalysis ? Give one example of ...

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  2. Write two differences between homogeneous catalysis and heterogeneous ...

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  3. Explain briefly homogeneous catalysis.

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  4. What do you understand by activity and selectivity of a catalyst ? Giv...

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  5. What is shape selective catalysis?

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  6. Describe some features of catalysis by zeolites.

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  7. How do enzymes differ from catalysts ?

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  8. What are Enzymes ? Give important characteristics of enzyme catalysis.

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  9. Give the mechanism of heterogeneous catalysed reaction.

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  10. Explain two applications of enzymes.

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  11. What are colloids ?

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  12. which are the properties of colloidal solution ?

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  13. What is the difference between true solution and colloidal solution?

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  14. Give three differences between suspension and colloid solution.

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  15. Name the dispersed phase and dispersion mediumin fog.

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  16. Comment on the statement that “colloid is not a substance but a state ...

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  17. What are lyophilic and lyophobic sols ? Give one example of each. Why ...

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  18. What are gels ? Give an example of elastic and non-elastic gel.

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  19. How will you differentiate Lyophilic colloids from Lyophobic colloids?

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  20. Lyophillic colloids are more stable than lyophobic colloids. Explain.

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