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Which of the following is the strongest ...

Which of the following is the strongest Bronsted base ?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which of the following is the strongest Bronsted base, we will analyze the options based on the availability of lone pair electrons for donation. A Bronsted base is defined as a species that can accept protons (H⁺) and the strength of a Bronsted base is related to the availability of its electrons for donation. ### Step-by-Step Solution: 1. **Identify the Options**: Let's assume we have four options (A, B, C, D) containing nitrogen compounds with varying lone pair electron availability. 2. **Analyze Option A**: - This nitrogen has a lone pair of electrons, but they are involved in resonance (delocalized). - **Conclusion**: Since the lone pair is not available for donation, this option is not a strong base. 3. **Analyze Option B**: - This nitrogen has a lone pair of electrons that are localized (not involved in resonance). - **Conclusion**: This option can act as a good base due to the availability of the lone pair for donation. 4. **Analyze Option C**: - Similar to Option A, this nitrogen's lone pair is delocalized due to resonance. - **Conclusion**: This option is also not a strong base because the lone pair is not available for donation. 5. **Analyze Option D**: - This nitrogen has a localized lone pair and is also attached to electron-donating groups (inductive effect). - **Conclusion**: The presence of these +I groups increases the electron density and enhances the ability to donate electrons, making this option a strong base. 6. **Comparison**: - Options B and D are both good bases, but Option D is stronger due to the +I groups that increase electron density and donation capability. 7. **Final Answer**: - The strongest Bronsted base among the options is **Option D**.

To determine which of the following is the strongest Bronsted base, we will analyze the options based on the availability of lone pair electrons for donation. A Bronsted base is defined as a species that can accept protons (H⁺) and the strength of a Bronsted base is related to the availability of its electrons for donation. ### Step-by-Step Solution: 1. **Identify the Options**: Let's assume we have four options (A, B, C, D) containing nitrogen compounds with varying lone pair electron availability. 2. **Analyze Option A**: - This nitrogen has a lone pair of electrons, but they are involved in resonance (delocalized). ...
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