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H - C = C- H underset(H2SO4) overset(HgS...

`H - C = C- H underset(H_2SO_4) overset(HgSO_4)to (A) underset((2) H_3O^(o+)) overset((1) NH_3 + HCN)to(B)`, Product (B) of given reaction is :

A

Glycine

B

Alanine

C

valine

D

Leucine

Text Solution

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The correct Answer is:
To solve the problem, we will break down the reactions step by step and identify the products formed at each stage. ### Step 1: Hydration of Ethyne 1. **Starting Material**: Ethyne (C₂H₂) is our starting compound. 2. **Reagents**: We are using sulfuric acid (H₂SO₄) and mercuric sulfate (HgSO₄) as a catalyst. 3. **Reaction**: The reaction involves the hydration of ethyne, which means adding water (H₂O) across the double bond. 4. **Product Formation**: The product formed from this reaction is acetaldehyde (CH₃CHO), which is also known as ethanal. This is product A. ### Step 2: Reaction of Acetaldehyde with Ammonia and Hydrogen Cyanide 1. **Starting Material**: The product A (acetaldehyde, CH₃CHO) is now reacted with ammonia (NH₃) and hydrogen cyanide (HCN) in the presence of hydronium ions (H₃O⁺). 2. **Mechanism**: - The carbonyl group (C=O) of acetaldehyde is attacked by the nucleophile (HCN), leading to the formation of a cyanohydrin. - The reaction can be summarized as follows: - The H⁺ from H₃O⁺ adds to the oxygen of the carbonyl group, making it more electrophilic. - The CN⁻ from HCN attacks the carbon atom of the carbonyl, forming a cyanohydrin intermediate (CH₃CH(OH)CN). 3. **Product Formation**: - The cyanohydrin can then react with excess ammonia. - The ammonia attacks the carbon atom, and a water molecule is eliminated, leading to the formation of an alpha-amino nitrile. - Upon hydrolysis (adding water), the alpha-amino nitrile will convert to an amino acid. - The final product formed is alanine (CH₃CH(NH₂)COOH), which is product B. ### Conclusion The product (B) of the given reaction is alanine (CH₃CH(NH₂)COOH). ### Final Answer Product (B) is **alanine**. ---

To solve the problem, we will break down the reactions step by step and identify the products formed at each stage. ### Step 1: Hydration of Ethyne 1. **Starting Material**: Ethyne (C₂H₂) is our starting compound. 2. **Reagents**: We are using sulfuric acid (H₂SO₄) and mercuric sulfate (HgSO₄) as a catalyst. 3. **Reaction**: The reaction involves the hydration of ethyne, which means adding water (H₂O) across the double bond. 4. **Product Formation**: The product formed from this reaction is acetaldehyde (CH₃CHO), which is also known as ethanal. This is product A. ...
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