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The Newman projection formula of most st...

The Newman projection formula of most stable conformation 3-Hydroxypropanal is gauche. It is stable due to :

A

minimum torsional strain

B

intramolecular hydrogen bonding

C

minimum torsional strain and intramolecular hydrogen bonding

D

minimum steric strain

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The correct Answer is:
To determine why the gauche conformation of 3-hydroxypropanal is the most stable, we can follow these steps: ### Step 1: Understand the Structure of 3-Hydroxypropanal 3-Hydroxypropanal has the following structure: - It consists of a propanal backbone (three carbon atoms with an aldehyde group at one end) and a hydroxyl (OH) group attached to the third carbon. - The molecular formula can be represented as CH3-CH(OH)-CH2-CHO. ### Step 2: Draw the Newman Projection To analyze the conformations, we draw the Newman projection: - Identify the front and back carbon atoms. In this case, we will consider the carbon atoms of the aldehyde group and the carbon with the hydroxyl group. - The front carbon (C1) has the aldehyde group (CHO) and the back carbon (C2) has the hydroxyl group (OH). ### Step 3: Identify the Conformations - The most stable conformation is the gauche conformation, which occurs when the bulky groups (OH and CHO) are staggered but close enough to allow for intramolecular hydrogen bonding. - The other conformations include fully eclipsed and fully staggered forms, which are less stable due to increased torsional strain. ### Step 4: Analyze Stability Factors - The stability of the gauche conformation can be attributed to the presence of intramolecular hydrogen bonding between the hydroxyl group (OH) and the carbonyl oxygen (C=O). - This hydrogen bonding stabilizes the molecule by lowering the energy of the system. ### Step 5: Conclusion The most stable conformation of 3-hydroxypropanal is the gauche conformation due to the presence of intramolecular hydrogen bonding, which provides additional stability compared to other conformations. ### Final Answer The gauche conformation of 3-hydroxypropanal is stable due to intramolecular hydrogen bonding. ---
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