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Which of the following will not show opt...

Which of the following will not show optical isomerism ?

A

`Cl-CH=C=CH-Cl`

B

`Br-CH=C=CH-Br`

C

D

Text Solution

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The correct Answer is:
To determine which of the given compounds does not show optical isomerism, we need to analyze each compound for the presence of a plane of symmetry. Optical isomerism occurs when a molecule can exist in two non-superimposable mirror images, which typically happens when there is no plane of symmetry in the molecule. ### Step-by-Step Solution: 1. **Understand Optical Isomerism**: - Optical isomerism arises in compounds that lack a plane of symmetry. If a compound has a plane of symmetry, it cannot have optical isomers. 2. **Analyze Each Compound**: - **Compound A**: - Structure: C1=C2 (with Cl and H on C1 and C2). - Analysis: If the two terminal carbons have different groups, this compound will show optical isomerism because it lacks a plane of symmetry. - **Compound B**: - Structure: C1=C2 (with Br and H on C1 and C2). - Analysis: Similar to Compound A, if the two terminal carbons have different groups, this compound will also show optical isomerism due to the absence of a plane of symmetry. - **Compound C**: - Structure: Fischer projection with groups COOH, H, OH. - Analysis: This compound has a plane of symmetry that divides it into two equal halves, making it optically inactive. Therefore, it does not show optical isomerism. - **Compound D**: - Structure: Newman projection converted to Fischer projection. - Analysis: After conversion, if there are no identical groups on the same carbon and no plane of symmetry, this compound will show optical isomerism. 3. **Conclusion**: - The only compound that does not show optical isomerism is **Compound C** due to the presence of a plane of symmetry. ### Final Answer: The compound that will not show optical isomerism is **Compound C**.

To determine which of the given compounds does not show optical isomerism, we need to analyze each compound for the presence of a plane of symmetry. Optical isomerism occurs when a molecule can exist in two non-superimposable mirror images, which typically happens when there is no plane of symmetry in the molecule. ### Step-by-Step Solution: 1. **Understand Optical Isomerism**: - Optical isomerism arises in compounds that lack a plane of symmetry. If a compound has a plane of symmetry, it cannot have optical isomers. 2. **Analyze Each Compound**: ...
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