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The structure of (S)-2-fluorobutane is b...

The structure of (S)-2-fluorobutane is best represented by:

A

`CH_(3) underset(F) underset(|)(C)HCH_(2)CH_(3)`

B

C

D

Text Solution

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The correct Answer is:
To determine the structure of (S)-2-fluorobutane from the given options, we will follow these steps: ### Step 1: Understand the Structure of 2-Fluorobutane 2-Fluorobutane is a four-carbon chain with a fluorine atom attached to the second carbon. The molecular formula is C4H9F. The stereogenic center is at the second carbon, which means it can exist in two enantiomeric forms: (R) and (S). ### Step 2: Identify the Chiral Center The second carbon (C-2) is the chiral center because it is attached to four different groups: 1. Fluorine (F) 2. Ethyl group (C2H5) 3. Methyl group (CH3) 4. Hydrogen (H) ### Step 3: Assign Priorities to the Groups Using the Cahn-Ingold-Prelog priority rules, we assign priorities based on atomic number: 1. Fluorine (F) - highest priority (1) 2. Ethyl group (C2H5) - second priority (2) 3. Methyl group (CH3) - third priority (3) 4. Hydrogen (H) - lowest priority (4) ### Step 4: Determine the Configuration To determine whether the configuration is (R) or (S), we need to visualize the molecule in a way that places the lowest priority group (H) in the back (dashed). ### Step 5: Visualize the Molecule In the wedge-dash representation: - The fluorine is at the top (1) - The ethyl group is on the right (2) - The methyl group is on the left (3) - The hydrogen is in the back (dashed) ### Step 6: Analyze the Arrangement Now, if we look at the arrangement from the perspective of the highest priority (F) to the lowest priority (H), we can see the order: 1 (F) → 2 (C2H5) → 3 (CH3) This arrangement goes in a counterclockwise direction, which indicates that the configuration is (S). ### Step 7: Check the Given Options We need to check the options provided: - **Option 1**: Not in wedge-dash form (cannot determine configuration) - **Option 2**: Wedge-dash form but does not have H in the back - **Option 3**: Correctly represents (S)-2-fluorobutane - **Option 4**: Incorrectly represents the configuration ### Conclusion The structure of (S)-2-fluorobutane is best represented by **Option 3**. ---

To determine the structure of (S)-2-fluorobutane from the given options, we will follow these steps: ### Step 1: Understand the Structure of 2-Fluorobutane 2-Fluorobutane is a four-carbon chain with a fluorine atom attached to the second carbon. The molecular formula is C4H9F. The stereogenic center is at the second carbon, which means it can exist in two enantiomeric forms: (R) and (S). ### Step 2: Identify the Chiral Center The second carbon (C-2) is the chiral center because it is attached to four different groups: 1. Fluorine (F) ...
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