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The most stable conformation of 2, 3-dim...

The most stable conformation of 2, 3-dimethyl butane is :

A

B

C

D

none of these

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The correct Answer is:
To determine the most stable conformation of 2,3-dimethylbutane, we need to analyze the different conformations based on steric interactions, specifically the gauche interactions. Here’s a step-by-step solution: ### Step 1: Identify the Structure 2,3-dimethylbutane has the following structure: - It consists of a butane backbone (4 carbon atoms) with two methyl (CH3) groups attached to the second and third carbon atoms. ### Step 2: Draw Possible Conformations We can visualize the different conformations of 2,3-dimethylbutane by rotating around the carbon-carbon bonds. The main conformations to consider are: - Staggered conformations (where groups are positioned as far apart as possible) - Eclipsed conformations (where groups are positioned directly in front of each other) ### Step 3: Analyze Each Conformation - **Conformation A**: This conformation has three gauche interactions (repulsive interactions between the methyl groups). - **Conformation B**: This conformation has two gauche interactions. - **Conformation C**: This conformation again has three gauche interactions. ### Step 4: Determine Stability The stability of a conformation is inversely related to the number of repulsive interactions (gauche interactions in this case). The fewer the gauche interactions, the more stable the conformation. - Conformation A: 3 gauche interactions (less stable) - Conformation B: 2 gauche interactions (more stable) - Conformation C: 3 gauche interactions (less stable) ### Step 5: Conclusion Since Conformation B has the least number of gauche interactions (only 2), it is the most stable conformation of 2,3-dimethylbutane. **Final Answer**: The most stable conformation of 2,3-dimethylbutane is **Option B**. ---

To determine the most stable conformation of 2,3-dimethylbutane, we need to analyze the different conformations based on steric interactions, specifically the gauche interactions. Here’s a step-by-step solution: ### Step 1: Identify the Structure 2,3-dimethylbutane has the following structure: - It consists of a butane backbone (4 carbon atoms) with two methyl (CH3) groups attached to the second and third carbon atoms. ### Step 2: Draw Possible Conformations We can visualize the different conformations of 2,3-dimethylbutane by rotating around the carbon-carbon bonds. The main conformations to consider are: ...
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