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Which one of the following is most stabl...

Which one of the following is most stable?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which of the given conformations is the most stable, we need to analyze the interactions present in each conformation. Let's break down the analysis step by step. ### Step-by-Step Solution: 1. **Identify the Conformations**: - We have four conformations labeled A, B, C, and D. Each conformation has different orientations for the hydroxyl (OH) groups. 2. **Analyze Conformation A**: - In conformation A, both OH groups are in the axial position. - When we draw the hydrogen atoms in this conformation, we notice that there is a hydrogen bonding interaction between one of the axial hydrogens and the oxygen of the OH group. - This interaction is stabilizing, making conformation A potentially stable. 3. **Analyze Conformation B**: - In conformation B, both OH groups are in the equatorial position. - There are no significant interactions between the OH groups in this conformation, which means it lacks stabilizing or destabilizing interactions. 4. **Analyze Conformation C**: - In conformation C, one OH group is in the axial position and the other is in the equatorial position. - The axial OH group experiences 1,3-diaxial repulsion with the axial hydrogens, leading to destabilizing interactions. This makes conformation C less stable. 5. **Analyze Conformation D**: - In conformation D, one OH group is axial and the other is equatorial, similar to conformation C. - However, there are no significant interactions present in this conformation either, which means it also lacks stabilizing interactions. 6. **Compare Stability**: - Conformation A has stabilizing hydrogen bonding interactions. - Conformations B and D have no interactions, while conformation C has destabilizing interactions. - Therefore, conformation A is the most stable due to the presence of hydrogen bonding. ### Conclusion: The most stable conformation among the given options is **Conformation A**, which has hydrogen bonding interactions. ---

To determine which of the given conformations is the most stable, we need to analyze the interactions present in each conformation. Let's break down the analysis step by step. ### Step-by-Step Solution: 1. **Identify the Conformations**: - We have four conformations labeled A, B, C, and D. Each conformation has different orientations for the hydroxyl (OH) groups. 2. **Analyze Conformation A**: ...
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