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Which of the following will have a trans...

Which of the following will have a trans isomer?

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B

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D

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The correct Answer is:
To determine which of the given compounds will have a trans isomer, we need to understand the concept of geometrical isomerism, specifically cis and trans isomerism. Here’s a step-by-step solution: ### Step 1: Understand Geometrical Isomerism Geometrical isomerism occurs in compounds with restricted rotation around a double bond or in cyclic structures. The two types of geometrical isomers are: - **Cis Isomer**: Similar groups are on the same side of the double bond or ring. - **Trans Isomer**: Similar groups are on opposite sides of the double bond or ring. ### Step 2: Identify the Compounds Let’s analyze the compounds provided in the question (assuming they are given as options). We will determine if each compound can exhibit trans isomerism. ### Step 3: Analyze Each Compound 1. **Compound 1**: CH3-C=C-CH3 (with H on one side) - This compound can have a trans isomer because the two CH3 groups can be on opposite sides of the double bond. - **Conclusion**: This compound exhibits trans isomerism. 2. **Compound 2**: Cl-C=C-Cl - In this case, the two chlorine atoms can be on opposite sides of the double bond, allowing for a trans configuration. - **Conclusion**: This compound exhibits trans isomerism. 3. **Compound 3**: Cyclohexane with two methyl groups - If the methyl groups are positioned on opposite sides of the cyclohexane ring, this configuration represents a trans isomer. - **Conclusion**: This compound exhibits trans isomerism. 4. **Compound 4**: A compound with two identical substituents on one side of the double bond (e.g., H-C=C-H) - Since both substituents are identical, it cannot exhibit geometrical isomerism. - **Conclusion**: This compound does not exhibit trans isomerism. ### Step 4: Final Answer Based on the analysis, the compounds that exhibit trans isomerism are: - Compound 1 - Compound 2 - Compound 3 Thus, the correct answer is that options 2, 3, and 4 will have a trans isomer. ---
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