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Among the following compounds which one ...

Among the following compounds which one will produce a Schiff base on reaction with cyclopentanone?

A

B

C

D

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The correct Answer is:
To determine which compound will produce a Schiff base upon reaction with cyclopentanone, we need to follow these steps: ### Step 1: Understand the Concept of Schiff Base A Schiff base is formed when a primary amine reacts with a carbonyl compound (like a ketone or aldehyde). The general reaction involves the nucleophilic attack of the amine on the carbonyl carbon, followed by the loss of water. ### Step 2: Identify the Reactants In this case, we are reacting cyclopentanone (a ketone) with a primary amine. Cyclopentanone has the structure: ``` O // C-C | | C-C ``` ### Step 3: Determine the Type of Amines We need to identify which of the given compounds is a primary amine. A primary amine has the structure R-NH2, where R is an alkyl or aryl group. ### Step 4: Analyze Each Compound - **Option A**: If it has two carbon groups attached to nitrogen (R1 and R2), it is a secondary amine. - **Option B**: If it has one carbon group and one hydrogen attached to nitrogen, it is a primary amine. - **Option C**: If it has two carbon groups attached to nitrogen, it is a secondary amine. - **Option D**: If it has three carbon groups attached to nitrogen, it is a tertiary amine. ### Step 5: Identify the Primary Amine From the analysis, we find that only **Option B** has the structure of a primary amine (R-NH2). ### Step 6: Confirm the Reaction Now, we can confirm that when cyclopentanone reacts with this primary amine, it will form a Schiff base. The reaction proceeds as follows: 1. The nitrogen of the primary amine attacks the carbonyl carbon of cyclopentanone. 2. A tetrahedral intermediate is formed. 3. Water is eliminated, resulting in the formation of the Schiff base. ### Conclusion Thus, the compound that will produce a Schiff base on reaction with cyclopentanone is **Option B**. ---

To determine which compound will produce a Schiff base upon reaction with cyclopentanone, we need to follow these steps: ### Step 1: Understand the Concept of Schiff Base A Schiff base is formed when a primary amine reacts with a carbonyl compound (like a ketone or aldehyde). The general reaction involves the nucleophilic attack of the amine on the carbonyl carbon, followed by the loss of water. ### Step 2: Identify the Reactants In this case, we are reacting cyclopentanone (a ketone) with a primary amine. Cyclopentanone has the structure: ...
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