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Which one of the following is used to id...

Which one of the following is used to identify glucose ?

A

Neutral `FeCl_3`

B

`CHCl_3 + KOH ` (alc.)

C

`C_2 H_5 O Na`

D

Ammoniacal `AgNO_3`

Text Solution

AI Generated Solution

The correct Answer is:
To identify glucose, we can use Tollens' reagent, which is also known as ammonical silver nitrate (AgNO3). Here’s a step-by-step explanation of how this works: ### Step 1: Understand the Nature of Glucose - Glucose is classified as a reducing sugar. This means it has the ability to donate electrons to other molecules, which is a key property that allows it to react with certain reagents. **Hint:** Remember that reducing sugars can reduce metal ions to their elemental form. ### Step 2: Identify the Reagents - The two common reagents used to identify reducing sugars are Tollens' reagent (ammonical AgNO3) and Fehling's solution. Both of these can be used to test for glucose. **Hint:** Look for reagents that are known to react with reducing sugars. ### Step 3: Reaction with Tollens' Reagent - When glucose is treated with Tollens' reagent, it reduces the silver ions (Ag+) present in the reagent to metallic silver (Ag), resulting in the formation of a shiny silver mirror on the surface of the test tube. **Hint:** A visual change, such as a silver mirror, indicates a positive test for glucose. ### Step 4: Write the Chemical Reaction - The reaction can be represented as follows: \[ \text{Glucose} + 2 \text{Ag}^+ + 3 \text{OH}^- \rightarrow \text{Gluconate ion} + 2 \text{Ag} + 2 \text{H}_2\text{O} \] - In this reaction, glucose is oxidized to gluconate ion, while silver ions are reduced to metallic silver. **Hint:** Pay attention to the products formed in the reaction, as they can help confirm the presence of glucose. ### Step 5: Conclusion - Therefore, the reagent used to identify glucose is ammonical AgNO3, which is Tollens' reagent. **Final Answer:** Ammonical AgNO3 (Tollens' reagent) is used to identify glucose.
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